Copper(II) Complexes Resulting from the Oxygenation of (2,9-Dimethyl-1,10-phenanthroline)copper(I) Chloride in the Presence of DImethylformamide

Kenichi Oyaizu; Masayoshi Ueno; Hong Li; Eishun Tsuchida

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Copper(II) Complexes Resulting from the Oxygenation of (2,9-Dimethyl-1,10-phenanthroline)copper(I) Chloride in the Presence of DImethylformamide

机译：在二甲基甲酰胺存在下由（2,9-二甲基-1,10-菲咯啉）氯化铜（I）氧化产生的铜（II）配合物

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The oxygenation of (2,9-dimethyl-1,10-phenanthroline)copper(I) chloride in THF,followed by a treatment with DMF and acidification wiht HCl,afforded dichloro[2-dimethylamino)(hydroxy)methyl-9-methyl-1,10-phenanthroline] copper(II) and (aqua)dichloro(2,9-dimethyl-1,10-phenanthroline)copper(II) quantitatively.

机译：（2,9-二甲基-1,10-菲咯啉）氯化铜（I）在THF中的氧化，然后用DMF处理并用HCl酸化，得到二氯[2-二甲基氨基）（羟基）甲基-9-甲基-1,10-菲咯啉]铜（II）和（水）二氯（2,9-二甲基-1,10-菲咯啉）铜（II）。

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《Bulletin of the Chemical Society of Japan》 |2001年第5期|共2页
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Kenichi Oyaizu; Masayoshi Ueno; Hong Li; Eishun Tsuchida;
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正文语种 eng
中图分类化学;化学工业;
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1. Copper(II) Complexes Resulting from the Oxygenation of (2,9-Dimethyl-1,10-phenanthroline)copper(I) Chloride in the Presence of DImethylformamide [J] . Kenichi Oyaizu, Masayoshi Ueno, Hong Li, Bulletin of the Chemical Society of Japan . 2001,第5期

机译：在二甲基甲酰胺存在下由（2,9-二甲基-1,10-菲咯啉）氯化铜（I）氧化产生的铜（II）配合物
2. Structural analysis and magnetic properties of the copper(II) dicyanamide complexes [Cu-2(dmphen)(2)(dca)(4)], [Cu(dmphen)(dca)(NO3)](n) and [Cu(4,4 '-dmbpy)(H2O)(dca)(2)] (dca = dicyanamide; dmphen=2,9-dimethyl-1,10-phenanthroline; 4,4 '-dmbpy=4,4 ' [J] . Carranza J, Sletten J, Lloret F, Inorganica Chimica Acta . 2004,第11期

机译：铜（II）双氰胺铜配合物[Cu-2（dmphen）（2）（dca）（4）]，[Cu（dmphen）（dca）（NO3）]（n）和[Cu（ 4,4'-dmbpy）（H2O）（dca）（2）]（dca =双氰胺; dmphen = 2,9-二甲基-1,10-菲咯啉; 4,4'-dmbpy = 4,4'
3. DYNAMICS OF THE COORDINATION EQUILIBRIA IN SOLUTIONS CONTAINING COPPER(II), COPPER(I), AND 2,9-DIMETHYL-1,10-PHENANTHROLINE AND THEIR EFFECT ON THE REDUCTION OF O-2 BY CU(I) [J] . Lei YB., Anson FC. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1995,第5期

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4. Structural Analysis of Polymeric Copper(II)-Pyrazinamide Complexes Prepared from Two Different Copper(II) Salts [C] . Mohammad Misbah Khunur, Yuniar Ponco Prananto Annual Basic Science International Conference . 2019

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5. Electron-transfer kinetics of copper(II/I) complexes with the ligands 1,10-phenanthroline, 2,2'-bipyridine and their derivatives in acetonitrile. [D] . McGillivary, Michael P. 2006

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7. Synthesis, Structural, and Cytotoxic Properties of New Water-Soluble Copper(II) Complexes Based on 2,9-Dimethyl-1,10-Phenanthroline and Their One Derivative Containing 1,3,5-Triaza-7-Phosphaadamantane-7-Oxide [O] . Ewelina I. Śliwa, Urszula Śliwińska-Hill, Barbara Bażanów, 2020

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机译：5-三氟甲基四唑阴离子与一些二价过渡金属离子形成的配合物的研究。一些取代苯甲酸铜（Ⅱ）配合物的磁化学和光谱研究。具有取代的吡啶n-氧化物的铜（II）卤化物配合物

Copper(II) Complexes Resulting from the Oxygenation of (2,9-Dimethyl-1,10-phenanthroline)copper(I) Chloride in the Presence of DImethylformamide

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