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首页> 外文期刊>Bulletin of the Chemical Society of Japan >X-Ray Analyses of Complexes Formed between Surfactants and Aromatic Compounds. I. A Common Structural Pattern of the Complexes
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X-Ray Analyses of Complexes Formed between Surfactants and Aromatic Compounds. I. A Common Structural Pattern of the Complexes

机译:表面活性剂和芳香族化合物之间形成的复合物的X射线分析。一,复合物的常见结构模式

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The cationic surfactants such as hexadecyl-, tetradecyl-, dodecyl-, and decyltrimethylammonium bromides form complexes with a variety of aromatic compounds in aqueous solutions Well-defined crystals were obtained if the aromatic compounds had hydrogen donor moieties. The structures of ten kinds of the complex crystals were analyzed by X-rays. All the crystal structures had a common pattern of complex formation, in which the aromatic compounds are sandwiched by the two alkyl chains of the surfactant molecules. There are two modes of stacking when the complexes with the common pattern are piled up to form the crystalline lattice. The common pattern of complex formation is responsible for the high viscoelasticity of the aqueous solutions containing cationic surfactants and aromatic compounds.
机译:阳离子表面活性剂(如十六烷基,十四烷基,十二烷基和癸基三甲基溴化铵)与多种芳族化合物在水溶液中形成配合物,如果芳族化合物具有氢供体部分,则可获得明确定义的晶体。用X射线分析了十种复杂晶体的结构。所有晶体结构都具有形成复合物的共同模式,其中芳族化合物被表面活性剂分子的两个烷基链夹在中间。当具有共同图案的复合物堆积形成晶格时,有两种堆积方式。络合物形成的常见模式是含有阳离子表面活性剂和芳族化合物的水溶液的高粘弹性的原因。

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