Conversion of 2-Aminoethanethio-late (aet) to 2-Benzoylaminoethane-thiolate (L) in a S-Bridged Diruthe-nium(II) Complex Composed of Two cis-[Ru(bpy)_2] Units.Crystal Structures of DELTA DELTA/LAMBDA LAMBDA-[{Ru(bpy)_2}_2 centre dot (mu-Haet)_2]~(4+)

Noriyuki Matsuura; Tatsuya Kawamoto; Takumi Konno

首页> 外文期刊>Bulletin of the Chemical Society of Japan >Conversion of 2-Aminoethanethio-late (aet) to 2-Benzoylaminoethane-thiolate (L) in a S-Bridged Diruthe-nium(II) Complex Composed of Two cis-[Ru(bpy)_2] Units.Crystal Structures of DELTA DELTA/LAMBDA LAMBDA-[{Ru(bpy)_2}_2 centre dot (mu-Haet)_2]~(4+)

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Conversion of 2-Aminoethanethio-late (aet) to 2-Benzoylaminoethane-thiolate (L) in a S-Bridged Diruthe-nium(II) Complex Composed of Two cis-[Ru(bpy)_2] Units.Crystal Structures of DELTA DELTA/LAMBDA LAMBDA-[{Ru(bpy)_2}_2 centre dot (mu-Haet)_2]~(4+)

机译：在由两个顺式[Ru（bpy）_2]单元组成的S桥连二钌（II）络合物中，将2-氨基乙硫基硫酸盐（aet）转化为2-苯甲酰基氨基乙烷硫醇盐（L）。DELTADELTA的晶体结构/ LAMBDA LAMBDA-[{Ru（bpy）_2} _2中心点（mu-Haet）_2]〜（4+）

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A diruthenium(II) complex,DELTA DELTA/LAMBDA LAMBDA-[(Ru(bpy)_2)_2(mu-L)_2]~(2+) (DELTA DELTA /LAMBDA LAMBDA-[2]~(2+)),in which two cis-[Ru(bpy)_2]~(2+) units are bridged by two S atoms from two 2-benzoylaminoethane-thiolate (L) ligands,was synthesized by the reaction of DELTA DELTA /LAMBDA LAMBDA-[{Ru(bpy)_2}_2(mu-Haet)_2]~(4+) (act=2-aminoethane-thiolate;DELTA DELTA /LAMBDA LAMBDA-[1]~(4+)) with benzoyl chloride in the presence of a base.The molecular structure and electrochemical properties of DELTA DELTA /LAMBDA LAMBDA-[2]~(2+) were discussed in comparison with those of DELTA DELTA /LAMBDA LAMBDA-[1]~(4+).

机译：钌（II）配合物，DELTA DELTA / LAMBDA LAMBDA-[（Ru（bpy）_2）_2（mu-L）_2]〜（2+）（DELTA DELTA / LAMBDA LAMBDA- [2]〜（2+））通过DELTA DELTA / LAMBDA LAMBDA- [1]反应合成了两个顺式[Ru（bpy）_2]〜（2+）单元被两个2-苯甲酰基氨基乙烷-硫醇盐（L）配体的两个S原子桥接。 {Ru（bpy）_2} _2（mu-Haet）_2]〜（4+）（act = 2-氨基乙烷-硫醇盐; DELTA DELTA / LAMBDA LAMBDA- [1]〜（4+））与苯甲酰氯的存在与DELTA DELTA / LAMBDA LAMBDA- [1]〜（4+）的分子结构和电化学性质进行了比较。

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《Bulletin of the Chemical Society of Japan》 |2006年第2期|共3页
作者
Noriyuki Matsuura; Tatsuya Kawamoto; Takumi Konno;
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1. Conversion of 2-Aminoethanethio-late (aet) to 2-Benzoylaminoethane-thiolate (L) in a S-Bridged Diruthe-nium(II) Complex Composed of Two cis-[Ru(bpy)_2] Units.Crystal Structures of DELTA DELTA/LAMBDA LAMBDA-[{Ru(bpy)_2}_2 centre dot (mu-Haet)_2]~(4+) [J] . Noriyuki Matsuura, Tatsuya Kawamoto, Takumi Konno Bulletin of the Chemical Society of Japan . 2006,第2期

机译：在由两个顺式[Ru（bpy）_2]单元组成的S桥连二钌（II）络合物中，将2-氨基乙硫基硫酸盐（aet）转化为2-苯甲酰基氨基乙烷硫醇盐（L）。DELTADELTA的晶体结构/ LAMBDA LAMBDA-[{Ru（bpy）_2} _2中心点（mu-Haet）_2]〜（4+）
2. Characterization and electrochemical properties for rhenium(III) ion incorporated into linear-type S-bridged trinuclear complexes. Crystal structures of Delta Lambda- and Delta Delta/Lambda Lambda-[Re{Ir(aet)(3)}(2)](3+) (aet=2-aminoethanethiolate) [J] . Mahboob N., Miyashita Y., Yamada Y., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2002,第18期

机译：linear（III）离子掺入线性S桥三核络合物的表征和电化学性能。 δLambda-和Delta Delta / Lambda Lambda- [Re {Ir（aet）（3）}（2）]（3+）（aet = 2-氨基乙烷硫醇盐）的晶体结构
3. Crystal structure analysis and chiral recognition study of Delta-[Ru(bpy)(2)(py)(2)][(+)-O,O '-dibenzoyl-D-tartrate]center dot 12H(2)O and Lambda-[Ru(bpy)(2)(py)(2)][(-)-O,O '-dibenzoyl-L-tartrate]center dot 12H(2)O [J] . Kolp B., von Zelewsky A., Abeln D., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2001,第6期

机译：δ-[Ru（bpy）（2）（py）（2）] [（+）-O，O'-二苯甲酰基-D-酒石酸盐]中心点12H（2）O和Lambda的晶体结构分析和手性识别研究-[Ru（bpy）（2）（py）（2）] [（-）-O，O'-二苯甲酰基-L-酒石酸盐]中心点12H（2）O

Conversion of 2-Aminoethanethio-late (aet) to 2-Benzoylaminoethane-thiolate (L) in a S-Bridged Diruthe-nium(II) Complex Composed of Two cis-[Ru(bpy)_2] Units.Crystal Structures of DELTA DELTA/LAMBDA LAMBDA-[{Ru(bpy)_2}_2 centre dot (mu-Haet)_2]~(4+)

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