Novel Through-Space Conjugated Polymers Consisting of Alternate [2.2]Paracyclophane and Fluorene

Yasuhiro Morisaki; Yoshiki Chujo

首页> 外文期刊>Bulletin of the Chemical Society of Japan >Novel Through-Space Conjugated Polymers Consisting of Alternate [2.2]Paracyclophane and Fluorene

【24h】

Novel Through-Space Conjugated Polymers Consisting of Alternate [2.2]Paracyclophane and Fluorene

机译：由交替的[2.2]环环烷和芴组成的新型贯穿空间共轭聚合物

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Novel through-space pi-conjugated polymers having [2.2]paracyclophane and fluorene units were synthesized by the Suzuki coupling reaction.The polymers possessed good solubility in common organic solvents and good thermal stability.According to the UV-vis absorption spectra,the polymer showed an extension of pi-delocalization via the through-space with TT-TT stacking compared with two kinds of model compounds.All of the polymers exhibited purplish-blue emission with high photoluminescence(PL)efficiencies of 73-81%in solution.The HOMO and LUM0 energy levels of the polymer were estimated from the cyclic voltammogram.

机译：通过Suzuki偶联反应合成了具有[2.2]对环环和芴单元的新型空位π共轭聚合物。该聚合物在常见有机溶剂中具有良好的溶解性和良好的热稳定性。根据紫外可见吸收光谱，该聚合物表现出与两种模型化合物相比，通过TT-TT叠层通过贯通空间进行pi离域化的扩展。所有聚合物均显示出紫蓝色发射，并在溶液中具有73-81％的高光致发光（PL）效率。聚合物的LUMO能级和LUMO能级由循环伏安图估算。

著录项

来源
《Bulletin of the Chemical Society of Japan》 |2005年第2期|共6页
作者
Yasuhiro Morisaki; Yoshiki Chujo;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词

相似文献

外文文献
中文文献
专利

1. Novel Through-Space Conjugated Polymers Consisting of Alternate [2.2]Paracyclophane and Fluorene [J] . Yasuhiro Morisaki, Yoshiki Chujo Bulletin of the Chemical Society of Japan . 2005,第2期

机译：由交替的[2.2]环环烷和芴组成的新型贯穿空间共轭聚合物
2. [2.2]paracyclophane-based through-space conjugated polymers with fluorescence quenchers [J] . Morisaki Y., Ueno S., Chujo Y. Journal of Polymer Science, Part A. Polymer Chemistry . 2013,第2期

机译：[2.2]基于对环环烷的空域共轭聚合物，带有荧光猝灭剂
3. Synthesis of Through-Space Conjugated Polymers Containing [2.2]Paracyclophane and Thieno[3,4-b]pyrazine in the Main Chain [J] . LIN LIN, YASUHIRO MORISAKI, YOSHIKI CHUJO Journal of Polymer Science, Part A. Polymer Chemistry . 2009,第24期

机译：主链含[2.2]环环烷和噻吩并[3,4-b]吡嗪的空域共轭聚合物的合成
4. Synthesis and Properties of Novel Through-Space Conjugated Polymer with 2.2Paracyclophane and Ferrocene in the Main Chain [C] . Yasuhiro Morisaki, Yoshiki Chujo Symposium on Organometallic Chemistry . 2003

机译：具有2.2截晶烷和主要链中的新型通过空间缀合聚合物的合成与性能和主链中的二茂铁
5. Synthetic routes to novel conjugated polymers based on fluorene and synthetic analogues of fluorene [D] . Brookins, Robert Neal 2008

机译：基于芴和芴合成类似物的新型共轭聚合物的合成路线
6. π-Stacked Polymer Consisting of a Pseudo–meta–[2.2]Paracyclophane Skeleton [O] . Hazuki Maeda, Mayu Kameda, Takuji Hatakeyama, 2011

机译：伪元– [2.2]芳环骨架的π堆积聚合物。
7. Through-space conjugated polymer containing 2.2paracyclophane and dithiafulvene units in the main chain [O] . Morisaki Yasuhiro, Lin Lin, Chujo Yoshiki 2009

机译：在主链中包含2.2对环烷和二硫富烯单元的空域共轭聚合物
8. Organotransition-Metal Metallacarboranes. 8. Mono-, Di-, and Triiron Polyarene Sandwich Complexes of Et2C2B4H4(2-) Containing Fluorene, 9,10-Dihydroanthracene, or (2.2)Paracyclophane Ligands [R] . Spencer, J. T., Grimes, R. N. 1987

机译：有机过渡 - 金属金属碳硼烷。 8.含有芴，9,10-二氢蒽或（2.2）对环芳烷配体的Et2C2B4H4（2-）的单 - ，二 - 和三铁聚芳烃夹心复合物

Novel Through-Space Conjugated Polymers Consisting of Alternate [2.2]Paracyclophane and Fluorene

摘要

著录项

相似文献

相关主题

期刊订阅