Palladium-Catalyzed Carboacylation of Alkenes by Using Acylchromates as Acyl Donors

Motoki Yamane; Yuko Kubota; Koichi Narasaka

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Palladium-Catalyzed Carboacylation of Alkenes by Using Acylchromates as Acyl Donors

机译：酰基铬酸盐作为酰基给体的钯催化烯烃的羰基化反应

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Palladium-catalyzed arylacylation of alkenes proceeds by employing acylchromates as acyl donors.When active alkenes such as norbornene and methoxyallene are treated with an aryl iodide,an acylchromate,and a catalytic amount of Pd(OAc)_2/2P(o-Tol)_3,arylacylation of these alkenes proceeds at room temperature.From aryl iodides having an intramolecular alkene moiety,cyclization-acylation products are obtained via intramolecular arylpalladation followed by acylation with acylchromates.

机译：钯催化的烯基芳基酰化反应是通过使用酰基铬酸酯作为酰基供体进行的。当将活性降碳烯（如降冰片烯和甲氧基丙二烯）用芳基碘化物处理时，酰基铬酸酯和催化量的Pd（OAc）_2 / 2P（o-Tol）_3这些烯烃的芳基酰化反应是在室温下进行的。从具有分子内烯烃部分的芳基碘化物，通过分子内芳基palpalation，然后用酰基铬酸酯进行酰化，得到环化-酰化产物。

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《Bulletin of the Chemical Society of Japan》 |2005年第2期|共10页
作者
Motoki Yamane; Yuko Kubota; Koichi Narasaka;
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正文语种 eng
中图分类化学;
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1. Palladium-Catalyzed Carboacylation of Alkenes by Using Acylchromates as Acyl Donors [J] . Motoki Yamane, Yuko Kubota, Koichi Narasaka Bulletin of the Chemical Society of Japan . 2005,第2期

机译：酰基铬酸盐作为酰基给体的钯催化烯烃的羰基化反应
2. Tetrahydroxydiboron-Mediated Palladium-Catalyzed Transfer Hydrogenation and Deuteriation of Alkenes and Alkynes Using Water as the Stoichiometric H or D Atom Donor [J] . Steven P. Cummings, Thanh-Ngoc Le, Gilberto E. Fernandez, Journal of the American Chemical Society . 2016,第19期

机译：四羟基二硼介导的钯催化的水或化学计量的H或D原子供体对烯烃和炔烃的钯催化转移氢化和氘化
3. Neutral Ligands with Exceptional Donor Ability for Palladium-Catalyzed Alkene Hydrogenation [J] . Marion Heckenroth, Evelyne Kluser, Antonia Neels Angewandte Chemie . 2007,第33期

机译：具有出色供体能力的中性配体，用于钯催化的烯烃加氢
4. Coupling Reactions of Alcohol, Electron-donor Alkene, and Electron-acceptor Alkene by Photoinduced Electron Transfer [C] . Yosuke Tanaka, Yasuharu Yoshimi 日本化学会春季年会講演予稿集 . 2018

机译：醇，电子给体烯烃和电子受体烯烃的偶联反应通过光导电的电子转移
5. Mechanistic studies of palladium-catalyzed 'Wacker type' intramolecular aerobic oxidative amination of alkenes and Development of safe and scalable continuous-flow methods for palladium-catalyzed aerobic oxidation [D] . Ye, Xuan 2010

机译：钯催化烯烃的“ Wacker型”分子内需氧氧化胺化的机理研究和开发安全，可扩展的连续流法进行钯催化的需氧氧化
6. Intermolecular selective carboacylation of alkenes via nickel-catalyzed reductive radical relay [O] . Xian Zhao, Hai-Yong Tu, Lei Guo, -1

机译：镍催化还原自由基中继的烯烃分子间选择性碳酰化
7. Neutral ligands with exceptional donor ability for Palladium-catalyzed alkene hydrogenation [O] . Heckenroth, Marion, Kluser, Evelyne, Neels, Antonia, 2008

机译：中性配体具有出色的供体能力，可用于钯催化的烯烃加氢

Palladium-Catalyzed Carboacylation of Alkenes by Using Acylchromates as Acyl Donors

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