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Chemical characterization and phase behaviour of grape seed oil in compressed carbon dioxide and ethanol as co-solvent

机译:葡萄籽油在压缩二氧化碳和乙醇中作为助溶剂的化学表征和相行为

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摘要

The aim of this work is to report phase equilibrium experimental results for the systems grape oil/carbon dioxide and (grape oil/carbon dioxide + ethanol). The oil was obtained by supercritical extraction from the grape seed residue from wine production. The static synthetic method using a variable-volume view cell was employed for obtaining the experimental bubble and dew (cloud) points transition data over the temperature range of (313.15 to 343.15) K and pressures up to 20.6 MPa. The experiments were carried out using (ethanol + CO_2) overall mass fractions ranging from 0.50 to 0.99, keeping a fixed ethanol to carbon dioxide molar ratio at 1:3. Results indicate the existence of complex phase behaviour for all temperatures investigated with the occurrence of vapour-liquid, liquid-liquid and vapour-liquid-liquid phase transitions observed.
机译:这项工作的目的是报告葡萄油/二氧化碳和(葡萄油/二氧化碳+乙醇)系统的相平衡实验结果。该油是通过超临界萃取从葡萄酒生产中的葡萄籽残渣中获得的。采用可变容积视场的静态合成方法来获得在(313.15至343.15)K的温度范围内和最高20.6 MPa的压力下的实验气泡和露点(浊点)转变数据。使用(乙醇+ CO_2)的总质量分数为0.50至0.99进行实验,并保持固定的乙醇与二氧化碳摩尔比为1:3。结果表明,在所观察到的所有温度下,均存在复杂的相行为,并观察到蒸气-液体,液体-液体和蒸气-液体-液体的相变。

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