...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>The Journal of Chemical Thermodynamics >Measurement and correlation of solubility of anthraquinone dyestuffs in supercritical carbon dioxide
【24h】

Measurement and correlation of solubility of anthraquinone dyestuffs in supercritical carbon dioxide

机译：蒽醌染料在超临界二氧化碳中的溶解度测定与相关

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Solubility data of 1,4-diaminoanthraquinone (C.I. Disperse Violet 1) and 1,4-bis(ethylamino)anthraquinone (C.I. Solvent Blue 59) in supercritical carbon dioxide (sc-CO_2) have been measured at the temperatures of (323.15, 353.15, and 383.15) K and over the pressure range from (12.5 to 25.0) MPa by a flow-type apparatus. The solubility of two anthraquinone dyestuffs was obtained over the mole fraction ranges of (1.3 to 26.1) ? 10~(-7) for 1,4-diaminoanthraquinone (C.I. Disperse Violet 1) and (1.1 to 148.5) ? 10~(-7) for 1,4-bis(ethylamino)anthraquinone (C.I. Solvent Blue 59). The experimental results have been correlated with the empirical equations of Mendez-Santiago-Teja and Kumar-Johnston expressed in terms of the density of sc-CO_2, and also analyzed thermodynamically by the regular solution model with the Flory-Huggins theory and the Peng-Robinson equation of state modified by Stryjek and Vera (PRSV-EOS) with the conventional mixing rules. Good agreement between the experimental and calculated solubilities of the dyestuffs was obtained.
机译：在（323.15，353.15）的温度下测量了1,4-二氨基蒽醌（CI分散紫1）和1,4-双（乙基氨基）蒽醌（CI溶剂蓝59）在超临界二氧化碳（sc-CO_2）中的溶解度数据;和383.15）K，并且通过流动型设备在（12.5至25.0）MPa的压力范围内。在摩尔分数范围为（1.3-26.1）≤1.0的范围内获得了两种蒽醌染料的溶解度。 1,4-二氨基蒽醌（C.I.分散紫1）和（1.1至148.5）的10〜（-7）？ 1,4-双（乙基氨基）蒽醌（C.I.溶剂蓝59）的10〜（-7）。实验结果与以sc-CO_2的密度表示的Mendez-Santiago-Teja和Kumar-Johnston的经验方程式相关，并且还采用了Flory-Huggins理论和Peng-Hardins的正解模型对热力学进行了分析。用常规混合规则由Stryjek和Vera（PRSV-EOS）修改的Robinson状态方程。在染料的实验和计算的溶解度之间获得了良好的一致性。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号