N-ACYLAMINOPHENYLCYCLOPROPANES IN REACTION WITH NITROUS ACID GENERATED in situ

S. S. Mochalov; R. A. Gazzaeva; A. Z. Kadzhaeva; A. N. Fedotov; E. V. Trofimova

首页> 外文期刊>Chemistry of heterocyclic compounds >N-ACYLAMINOPHENYLCYCLOPROPANES IN REACTION WITH NITROUS ACID GENERATED in situ

【24h】

N-ACYLAMINOPHENYLCYCLOPROPANES IN REACTION WITH NITROUS ACID GENERATED in situ

机译：原位产生的亚硝酸与N-乙酰氨基酚含量的丙烯酰胺反应

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The reaction of N-acylaminophenylcyclopropanes with HNO_2 proceeds regioselectively with introduction of an N=O fragment into the three-membered ring and formation of the corresponding Δ~2-isoxazolines. For ortho-substituted N-acylaminophenylcyclopropanes side processes were observed, caused by the intramolecular participation of the N-acyl group in conversions of the carbenium ions formed on opening the cyclopropane ring under the action of the nitrosating reagent, and by direct insertion of the modified ortho substituent into the three-membered ring.

机译：N-酰基氨基苯基环丙烷与HNO_2的反应在区域选择性地进行，将N = O片段引入三元环并形成相应的Δ〜2-异恶唑啉。对于邻位取代的N-酰基氨基苯基环丙烷，观察到副过程，这是由于N-酰基的分子内参与，在亚硝化试剂的作用下打开环丙烷环时形成的碳正离子的转化，以及通过直接插入修饰的邻取代基成三元环。

著录项

来源
《Chemistry of heterocyclic compounds》 |2012年第11期|共15页
作者
S. S. Mochalov; R. A. Gazzaeva; A. Z. Kadzhaeva; A. N. Fedotov; E. V. Trofimova;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类杂环化合物;
关键词
N-acylaminophenylcyclopropanes; 3; 1-benzoxazines; Δ~2-isoxazolines; heterocyclization;

机译：N-酰基氨基苯基环丙烷;3;1-苯并恶嗪;Δ〜2-异恶唑啉;杂环化;

相似文献

外文文献
中文文献
专利

1. N-ACYLAMINOPHENYLCYCLOPROPANES IN REACTION WITH NITROUS ACID GENERATED in situ [J] . S. S. Mochalov, R. A. Gazzaeva, A. Z. Kadzhaeva, Chemistry of heterocyclic compounds . 2012,第11期

机译：原位产生的亚硝酸与N-乙酰氨基酚含量的丙烯酰胺反应
2. Asymmetric Aza-Diels-Alder Reactions of in Situ Generated beta,beta-Disubstituted alpha,beta-Unsaturated N-H Ketimines Catalyzed by Chiral Phosphoric Acids [J] . He Shunlong, Gu Huanchao, He Yu-Peng, Organic letters . 2020,第14期

机译：原位生成的β，β二取代的α，β-不饱和N-H酮催化的不对称AZA-Diels - α-β-不饱和N-H酮磷酸
3. Efficient in situ N-heterocyclic carbene palladium(ii) generated from Pd(OAc)(2) catalysts for carbonylative Suzuki coupling reactions of arylboronic acids with 2-bromopyridine under inert conditions leading to unsymmetrical arylpyridine ketones: synthesis, characterization and cytotoxic activities (vol 8, pg 40000, 2018) [J] . Touj Nedra, Al-Ayed Abdullah S., Sauthier Mathieu, RSC Advances . 2019,第2期

机译：高效的原位N-杂环钯（II）从Pd（OAC）（2）碳酸苏氏氧化芳基偶联反应与2-溴吡啶的羰基·铃木偶联反应，导致非对称芳基吡啶酮：合成，表征和细胞毒性活性（Vol 8，PG 40000，2018）
4. Formation Integrity and Pore System Evaluation for Stimulated SandstoneFormation Using In-Situ Generated Acid Catalyzed by A Fused ChemicalReaction [C] . Ibrahim Gomaa SPE Annual Technical Conference and Exhibition . 2020

机译：用原位生成的融合化学反应催化刺激砂岩信息的形成完整性和孔隙系统评价
5. Reaction of calcite and dolomite with in-situ gelled acids, organic acids, and environmentally friendly chelating agent (GLDA) [D] . Rabie, Ahmed Ibrahim. 2012

机译：方解石和白云岩反应与原位凝胶酸，有机酸和环保螯合剂（GLDA）
6. Chiral Brønsted acid-catalyzed enantioselective Friedel–Crafts reaction of 2-methoxyfuran with aliphatic ketimines generated in situ [O] . Azusa Kondoh, Yusuke Ota, Takazumi Komuro, 2016

机译：手性布朗斯台德酸催化的2-甲氧基呋喃与原位生成的脂肪族酮亚胺的对映选择性Friedel-Crafts反应
7. Correction: Efficient in situ N-heterocyclic carbene palladium(ii) generated from Pd(OAc)2 catalysts for carbonylative Suzuki coupling reactions of arylboronic acids with 2-bromopyridine under inert conditions leading to unsymmetrical arylpyridine ketones: synthesis, characterization and cytotoxic activities [O] . Nedra Touj, Abdullah S. Al-Ayed, Mathieu Sauthier, 2019

机译：校正：从Pd（OAC）2催化剂中产生的芳基氨基酸的2-溴苯酸偶联反应的羰基酸胆碱偶联反应的高效惰性条件，导致非对称芳基吡啶酮：合成，表征和细胞毒性活性
8. Kinetic study of the mechanism of reactions of aromatic hydroxy compounds with nitrous acid and nitric acid in non aqueous solvents at various temperatures [R] . 1964

机译：不同温度下芳香族羟基化合物与亚硝酸和硝酸在非水溶剂中反应机理的动力学研究

N-ACYLAMINOPHENYLCYCLOPROPANES IN REACTION WITH NITROUS ACID GENERATED in situ

摘要

著录项

相似文献

相关主题

期刊订阅