Sulfenyl halides in the synthesis of heterocycles. 3. Interaction of perfluoro-1-ethyl-2-methyl-1-propenyl-iminochloromethanesulfenyl chloride with 1-allyl-2-methoxybenzene

A. V. Borisov; V. K. Belsky; V. K. Osmanov; G. N. Borisova; Zh. V. Matsulevich

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Sulfenyl halides in the synthesis of heterocycles. 3. Interaction of perfluoro-1-ethyl-2-methyl-1-propenyl-iminochloromethanesulfenyl chloride with 1-allyl-2-methoxybenzene

机译：硫杂环丁烷在杂环的合成中。 3.全氟-1-乙基-2-甲基-1-丙烯基-亚氨基氯甲烷亚磺酰氯与1-烯丙基-2-甲氧基苯的相互作用

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Reaction of perfluoro-1-ethyl-2-methyl-1-propenyliminochloromethanesulfenyl chloride with 1-allyl-2-methoxybenzene in methylene chloride and nitromethane gives as the main products β-and β-chloro sulfides plus derivative of 2,3-dihydrobenzofuran. The reaction in nitromethane in the presence of lithium perchlorate gave a product of addition of sulfur-containing electrophiles to the double bond-a derivative of 1,3-thiazolidin-2-one-in preference to the cycloaddition product.

机译：全氟-1-乙基-2-甲基-1-丙烯基亚氨基氯甲烷亚磺酰氯与1-烯丙基-2-甲氧基苯在二氯甲烷和硝基甲烷中的反应产生β-和β-氯硫化物以及2,3-二氢苯并呋喃衍生物。在高氯酸锂存在下在硝基甲烷中的反应产生了将含硫亲电试剂加成到双键上的产物，该双键是1，3-噻唑烷二-2-酮的衍生物，优先于环加成产物。

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《Chemistry of heterocyclic compounds》 |2006年第10期|共6页
作者
A. V. Borisov; V. K. Belsky; V. K. Osmanov; G. N. Borisova; Zh. V. Matsulevich;
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正文语种 eng
中图分类杂环化合物;
关键词
alkenes; sulfenyl chlorides; heterocyclization;

机译：烯烃;亚磺酰氯;杂环化;

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1. Sulfenyl halides in the synthesis of heterocycles. 3. Interaction of perfluoro-1-ethyl-2-methyl-1-propenyl-iminochloromethanesulfenyl chloride with 1-allyl-2-methoxybenzene [J] . A. V. Borisov, V. K. Belsky, V. K. Osmanov, Chemistry of heterocyclic compounds . 2006,第10期

机译：硫杂环丁烷在杂环的合成中。 3.全氟-1-乙基-2-甲基-1-丙烯基-亚氨基氯甲烷亚磺酰氯与1-烯丙基-2-甲氧基苯的相互作用
2. Sulfenyl Halides in the Synthesis of Heterocycles. 2. Cyclization in Reactions of Hetarenesulfenyl Chlorides with 3,3-Dimethyl-1-butene [J] . A. V. Borisov, V. K. Belsky, T. V. Goncharova, Chemistry of heterocyclic compounds . 2005,第6期

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3. Sulfenyl halides in the synthesis of heterocycles. 4. Heterocyclization in reactions of alkenes with sulfenylating reagents based on di(2-pyridyl) disulfide [J] . Borisov A.V., Matsulevich Z.V., Osmanov V.K., Chemistry of heterocyclic compounds . 2012,第7期

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Sulfenyl halides in the synthesis of heterocycles. 3. Interaction of perfluoro-1-ethyl-2-methyl-1-propenyl-iminochloromethanesulfenyl chloride with 1-allyl-2-methoxybenzene

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