Reaction of 4,6-dichloro-5-nitrobenzofuroxan with aromatic amines and nitrogen-containing heterocycles

Gibadullina E.M.; Chugunova E.A.; Mironova E.V.; Krivolapov D.B.; Burilov A.R.; Yusupova L.M.; Pudovik M.A.

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Reaction of 4,6-dichloro-5-nitrobenzofuroxan with aromatic amines and nitrogen-containing heterocycles

机译：4,6-二氯-5-硝基苯并呋喃与芳香胺和含氮杂环的反应

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摘要

4,6-Dichloro-5-nitrobenzofuroxan reacts with aromatic and heterocyclic amines via the chlorine atom at the position 4 of the aromatic ring to give monosubstitution products. In a similar reaction with piperazine, both amino groups undergo arylation to give a compound containing two benzofuroxan fragments.

机译：4，6-二氯-5-硝基苯并呋喃酮通过芳环第4位的氯原子与芳族和杂环胺反应，生成单取代产物。在与哌嗪的类似反应中，两个氨基均进行芳基化，得到含有两个苯并呋喃片段的化合物。

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来源
《Chemistry of heterocyclic compounds》 |2012年第8期|共7页
作者
Gibadullina E.M.; Chugunova E.A.; Mironova E.V.; Krivolapov D.B.; Burilov A.R.; Yusupova L.M.; Pudovik M.A.;
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正文语种 eng
中图分类杂环化合物;
关键词
Amination; Aromatic ring; Arylation; Benzofuroxan; Monosubstitution;

机译：胺化;芳环;芳基化;苯并呋喃;单取代;

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专利

1. Reaction of 4,6-dichloro-5-nitrobenzofuroxan with aromatic amines and nitrogen-containing heterocycles [J] . Gibadullina E.M., Chugunova E.A., Mironova E.V., Chemistry of heterocyclic compounds . 2012,第8期

机译：4,6-二氯-5-硝基苯并呋喃与芳香胺和含氮杂环的反应
2. Catalytic activity and antibacterial properties of nanopolymer-supported copper complex for C-N coupling reactions of amines and nitrogen-containing heterocycles with aryl halides [J] . Nasrollahzadeh Mahmoud, Zahraei Ali, Pourbasheer Eslam Monatshefte fur Chemie . 2015,第8期

机译：纳米聚合物负载的铜配合物对胺和含氮杂环与芳基卤化物的C-N偶联反应的催化活性和抗菌性能
3. Catalytic activity and antibacterial properties of nanopolymer-supported copper complex for C–N coupling reactions of amines and nitrogen-containing heterocycles with aryl halides [J] . Mahmoud Nasrollahzadeh, Ali Zahraei, Eslam Pourbasheer Monatshefte für Chemie - Chemical Monthly . 2015,第8期

机译：纳米聚合物负载的铜配合物对胺和含氮杂环与芳基卤化物的C–N偶联反应的催化活性和抗菌性能
4. Synthesis of Allenes Containing Heterocycles via Palladium-Catalyzed Hydrogen Transfer Reaction of Propargylic Amines [C] . Shinva Onagi, Hiroyuki Nakamura Symposium on Organometallic Chemistry . 2004

机译：通过钯催化的丙氨酸胺催化杂环含有杂环的烯丙烯醚的合成
5. Multicomponent reactions of allenyl and alkynyl boron derivatives with amines and aldehydes and their use in the synthesis of novel multifunctional amines and heterocycles [D] . Liepouri, Fotini 2007

机译：烯丙基和炔基硼衍生物与胺和醛的多组分反应及其在合成新型多功能胺和杂环中的应用
6. A Greener and Efficient Method for Nucleophilic Aromatic Substitution of Nitrogen-Containing Fused Heterocycles [O] . Joana F. Campos, Mohammed Loubidi, Marie-Christine Scherrmann, 2018

机译：含氮杂环杂环的亲核芳香取代的一种绿色高效方法
7. Prenylation of Aromatic Amines and Nitrogen-containing Aromatic Heterocycles by Prenyl Diisopropyl Phosphate [O] . Shuki Araki, Shin-ichi Manabe, Yasuo Butsugan 1984

机译：芳族胺和含氮芳族磷酸戊酰基的芳族芳族杂环

Reaction of 4,6-dichloro-5-nitrobenzofuroxan with aromatic amines and nitrogen-containing heterocycles

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