Wavelength-resolved stimulated photon echoes: Direct observation of ultrafast intramolecular vibrational contributions to electronic dephasing

Lesis D. Book; Norbert F. Scherer

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Wavelength-resolved stimulated photon echoes: Direct observation of ultrafast intramolecular vibrational contributions to electronic dephasing

机译：波长分辨的受激光子回波：超快分子内振动对电子相移的贡献的直接观察

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Novel wavelength-resolved stimulated photon echo measurements on a dye molecule in solution re presented. Data are simulated within the multimode Brownian oscillator model using the spectral density of de Boeij et al. [J. Phys. Chem. 100, 11806 (1996)] for the same solute-solvent system. For photon echo population times < 50 fs there are considerable differences between the measured and calculated data. Aided by further simulations, we conclude that these discrepancies result from dephasing dynamics of high frequency intramolecular vibrational modes not included in the previously derived spectral density.

机译：提出了对染料分子在溶液中的新型波长分辨激发光子回波测量方法。使用de Boeij等人的频谱密度在多模布朗振荡器模型中模拟数据。 [J.物理化学100，11806（1996）]。对于小于50 fs的光子回波填充时间，在测量数据和计算数据之间存在相当大的差异。借助进一步的模拟，我们得出结论，这些差异是由于移相了先前导出的频谱密度中未包括的高频分子内振动模式的动力学而导致的。

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《The Journal of Chemical Physics》 |1999年第3期|共4页
作者
Lesis D. Book; Norbert F. Scherer;
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中图分类物理化学（理论化学）、化学物理学;
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1. Wavelength-resolved stimulated photon echoes: Direct observation of ultrafast intramolecular vibrational contributions to electronic dephasing [J] . Lesis D. Book, Norbert F. Scherer The Journal of Chemical Physics . 1999,第3期

机译：波长分辨的受激光子回波：超快分子内振动对电子相移的贡献的直接观察
2. Direct Time-Domain Observation.of Ultrafast Dephasing in Adsorbate-Substrate Vibration under the Influence of a Hot Electron Bath: Cs Adatoms on Pt(111) [J] . Kazuya Watanabe, Noriaki Takagi, Yoshiyasu Matsumoto Physical review letters . 2004,第5期

机译：直接时域观察在热电子浴影响下超快速移相吸附物-基质振动：Ps（111）上的Cs原子原子
3. Vibrational dephasing of the -N=C=N- anti-symmetric stretching mode of carbodiimide studied by infrared photon echo method [J] . Maekawa H, Ohta K, Tominaga K Journal of Molecular Structure . 2005,第0期

机译：红外光子回波法研究碳二亚胺-N = C = N-反对称拉伸模的振动相移
4. Femtosecond photon echo as probe for ultrafast optical dephasing and optical band shape in condensed molecular systems [C] . I.S. Osadko, Moscow State Pedagogical Univ., Moscow, Coherent Phenomena and Amplification without Inversion . 1996

机译：飞秒光子回波作为探针用于凝聚分子系统中的超快光学相移和光带形状
5. Theoretical studies of the external vibrational control of electronic excitation transfer and its observation using polarization- and optical phase-sensitive ultrafast spectroscopy. [D] . Biggs, Jason Daniel. 2010

机译：电子激发转移的外部振动控制的理论研究及其使用偏振和光学相位敏感的超快光谱的观察。
6. Fifth-order contributions to ultrafast spectrally resolved vibrational echoes: Heme-CO proteins [O] . Ilya J. Finkelstein, Brian L. McClain, M. D. Fayer -1

机译：超快光谱分辨振动回波的五阶贡献：Heme-CO蛋白
7. Ultrafast Dynamics of Myoglobin without the Distal Histidine: Stimulated Vibrational Echo Experiments and Molecular Dynamics Simulations [O] . Roger F. Loring, M. D. Fayer 2005

机译：没有远端组氨酸的肌红蛋白超快动力学：受激振动回波实验和分子动力学模拟
8. Excess Dephasing in Photon Echo Experiments Arising from Excitation-Induced Electronic Level Shifts. [R] . Huang, J., Zhang, J. M., Lezama, A., 1989

机译：由激发引起的电子水平移位引起的光子回波实验中的过度缺相。

Wavelength-resolved stimulated photon echoes: Direct observation of ultrafast intramolecular vibrational contributions to electronic dephasing

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