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BOUND STATES IN ELECTROLYTE SOLUTIONS - THEORY OF ION ASSOCIATION

机译：电解质溶液中的键态-离子缔合理论

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A new concept of ion association in electrolyte solutions is presented in this paper. The starting point for our theory is the activity expansion of osmotic pressure in the physical picture and the energetic definition of bound states in the phase space of ions. The weight function describing the contributions of the bound states to the second cluster coefficients is calculated. It is established that ion screening has a substantial influence on the formation of bound states. The equation of state is written in the chemical picture by splitting the two-particle screened cluster coefficient into bound and free parts. We show that the bound part of the cluster coefficient in the physical picture can be identified with the association constant in the chemical picture. The mass action law is derived in a self-consistent way. (C) 1996 American Institute of Physics. [References: 34]
机译：本文提出了电解质溶液中离子缔合的新概念。我们理论的出发点是物理图中渗透压的活性扩展和离子相空间中键合态的高能定义。计算描述结合态对第二聚类系数的贡献的权重函数。已经证实，离子筛选对结合态的形成具有实质性影响。通过将两粒子筛选的簇系数分为有界部分和自由部分，将状态方程写在化学图中。我们表明，物理图片中簇系数的边界部分可以用化学图片中的缔合常数来识别。群众行动法则是自洽的。 （C）1996年美国物理研究所。 [参考：34]

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