IDENTIFICATION OF THE [(BPY)(2)RN(IM)(H2O)](2+) COMPLEX AS AN REACTION INTERMEDIATE BY REVERSED-PHASE HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY

Moreira IS.; Santiago MO.

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IDENTIFICATION OF THE [(BPY)(2)RN(IM)(H2O)](2+) COMPLEX AS AN REACTION INTERMEDIATE BY REVERSED-PHASE HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY

机译：反相高效液相色谱法鉴定[（BPY）（2）RN（IM）（H2O）]（2+）络合物作为反应中间体

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The synthesis of the complex [(bPY)(2)Ru(Im)(2)](2+)(bpy = 2,2'-bipyridine; Im = imidazole) has been monitored by reversed-phase HPLC. The analytical results obtained during the reaction have shown that it is feasible to identify and isolate the [(bPY)(2)RuIm(H2O)](2+) complex as a reaction intermediate. The optimization of the synthetic procedures for these two species has been established and the compounds have been obtained in high purity. The use of HPLC has enabled complete analytical control of the synthesis of the [(bpy)(2)RuL(2)](2+) class of compounds, enabling the identification of reaction intermediates. [References: 21]

机译：络合物[（bPY）（2）Ru（Im）（2）]（2 +）（bpy = 2,2'-联吡啶; Im =咪唑）的合成已通过反相HPLC进行了监测。反应期间获得的分析结果表明，鉴定和分离作为反应中间体的[（bPY）（2）RuIm（H2O）]（2+）配合物是可行的。已经确定了这两种物质的合成方法的优化，并且已经以高纯度获得了化合物。 HPLC的使用已实现对[[bpy]（2）RuL（2）]（2+）类化合物的合成的完整分析控制，从而能够鉴定反应中间体。 [参考：21]

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《Chromatographia》 |1996年第6期|共5页
作者
Moreira IS.; Santiago MO.;
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正文语种 eng
中图分类分析化学;
关键词
Column liquid chromatography; Ruthenium diimine complexes; Inorganic synthesis; Kinetics monitoring; Electron-transfer; Elution behavior; Excited-states; Ruthenium(ii); Derivatives; Iron(ii); Proteins; Ligands; Ion;

机译：柱液相色谱;钌二亚胺配合物;无机合成;动力学监测;电子转移;洗脱行为;激发态;钌（ii）;衍生物;铁（ii）;蛋白质;配体;离子;

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1. Infinite Three-Dimensional Coordination Polymers: Synthesis and Structures of Cd (4,4'-bpy)2 (H2O)2n (pic)2n, Zn (4,4'-bpy)2 (H2O)2 n-(pic)2n (H2O)2n, and Zn (4,4'-bpy)2 (H2O)2n (4,4'-bpy)n (H2O)n (pic)2n [J] . 中国化学快报（英文版） . 2000,第004期
2. IDENTIFICATION OF THE [(BPY)(2)RN(IM)(H2O)](2+) COMPLEX AS AN REACTION INTERMEDIATE BY REVERSED-PHASE HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY [J] . Moreira IS., Santiago MO. Chromatographia . 1996,第5a6期

机译：反相高效液相色谱法鉴定[（BPY）（2）RN（IM）（H2O）]（2+）络合物作为反应中间体
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6. The voltammetric and chemiluminescent characterization of a heptyl-thiol derivative of tris(2,2'-bipyridyl) ruthenium (II)(ruthenium(bpy)(3)(2+)), and, The use of in situ generated ruthenium(bpy)(3)(3+) for the chemiluminescent detection of native amino acids with application to liquid chromatography and capillary electrophoresis. [D] . Jackson, Warren Alan. 1994

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IDENTIFICATION OF THE [(BPY)(2)RN(IM)(H2O)](2+) COMPLEX AS AN REACTION INTERMEDIATE BY REVERSED-PHASE HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY

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