CHF↓(2)CI and CH↓(3)CF↓(2)Cl Detection by Coherent Anti-Stokes Raman Scattering and Photoacoustic Raman Spectroscopy

A. Melchior; I. Bar; S. Rosenwaks

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CHF↓(2)CI and CH↓(3)CF↓(2)Cl Detection by Coherent Anti-Stokes Raman Scattering and Photoacoustic Raman Spectroscopy

机译：相干反斯托克斯拉曼散射和光声拉曼光谱法检测CHF↓（2）CI和CH↓（3）CF↓（2）Cl

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The coherent anti-Stokes Raman scattering (CARS) and photoacoustic Raman spectroscopy (PARS) spectra of gaseous CHF↓(2)Cl and CH↓(3)CF↓(2)C1 in the 3000 cm↑(-1) region are reported for the first time. Several vibrational bands are observed related to C-H stretch fundamentals of CHF↓(2)C1 isotopomers, and to CH↓(3) stretches and the first overtone of CH↓(3) deformation of CH↓(3)CF↓(2)C1. The simultaneous detection of CARS/PARS signals aids the assignment of the isotopomer bands. Both methods are appropriate for detection of these compounds and can be applied in chemical dynamics studies.

机译：报告了气态CHF↓（2）Cl和CH↓（3）CF↓（2）C1在3000 cm↑（-1）区域的相干抗斯托克斯拉曼散射（CARS）和光声拉曼光谱（PARS）光谱首次。观察到几个与CHF↓（2）C1异构体的CH拉伸基本原理相关的振动带，以及与CH↓（3）拉伸和CH↓（3）CH↓（3）CF↓（2）C1变形的第一泛音相关的振动带。。同时检测CARS / PARS信号有助于分配同位素异构体。两种方法均适用于检测这些化合物，并可应用于化学动力学研究。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |1998年第40期|共4页
作者
A. Melchior; I. Bar; S. Rosenwaks;
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中图分类物理化学（理论化学）、化学物理学;
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1. CHF↓(2)CI and CH↓(3)CF↓(2)Cl Detection by Coherent Anti-Stokes Raman Scattering and Photoacoustic Raman Spectroscopy [J] . A. Melchior, I. Bar, S. Rosenwaks The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 1998,第37a40期

机译：相干反斯托克斯拉曼散射和光声拉曼光谱法检测CHF↓（2）CI和CH↓（3）CF↓（2）Cl
2. Compact fibre-based coherent anti-Stokes Raman scattering spectroscopy and interferometric coherent anti-Stokes Raman scattering from a single femtosecond fibre-laser oscillator [J] . Vikas Kumar, Alessio Gambetta, Cristian Manzoni, Pramana . 2010,第6期

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CHF↓(2)CI and CH↓(3)CF↓(2)Cl Detection by Coherent Anti-Stokes Raman Scattering and Photoacoustic Raman Spectroscopy

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