首页> 外文期刊>The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory >Characterization of Photoinduced Electron Transfer in Jet-Formed Acceptor Donor Complexes. 2. Photoinduced Electron Transfer: Rates and Mechanisms
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Characterization of Photoinduced Electron Transfer in Jet-Formed Acceptor Donor Complexes. 2. Photoinduced Electron Transfer: Rates and Mechanisms

机译:射流形成的受体供体配合物中的光诱导电子转移的表征。 2.光致电子转移:速率和机理

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摘要

The electron transfer (ET) rates induced by the electronic excitation of different isomers of anthracene complexes with aniline derivatives are deduced from their fluorescence and fluorescence excitation spectra. The shapes of potential energy surfaces of locally excited and ionic surfaces are calculated with a special interest for the crossing areas of both surfaces. The dependence of the ET rates on the initial configuration is discussed and the assignments of calculated configurations to isomeric species (E and R isomers) are proposed.
机译:由蒽络合物与苯胺衍生物的不同异构体的电子激发所诱导的电子传递(ET)速率可从其荧光和荧光激发光谱中推导出。计算局部激发和离子表面的势能表面的形状时,要特别注意两个表面的交叉区域。讨论了ET速率对初始构型的依赖性,并提出了将计算构型分配给异构体(E和R异构体)的方法。

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