...
首页> 外文期刊>The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory >Electric Field Effects of Fluorescence of Methylene-Linked Compounds of Phenanthrene and N,N-Dimethylaniline in a Poly(methyl methacrylate) Polymer Film
【24h】

Electric Field Effects of Fluorescence of Methylene-Linked Compounds of Phenanthrene and N,N-Dimethylaniline in a Poly(methyl methacrylate) Polymer Film

机译:聚甲基丙烯酸甲酯聚合物薄膜中菲与N,N-二甲基苯胺的亚甲基连接化合物的荧光电场效应

获取原文
获取原文并翻译 | 示例
           

摘要

Electric field effects of photoinduced electron-transfer processes have been examined in a polymer film for methylene-linked compounds of phenanthrene and N,N-dimethylaniline, based on the measurements of the field effects on fluorescence spectra. Both intra- and intermolecular electron-transfer processes are enhanced by an electric field (F), depending on the methylene chain length, and LE fluorescence emitted from the locally excited state of phenanthrene chromophore is quenched by F. Exciplex fluorescence is also influenced by F. The magnitude of the change in molecular polarizability following fluorescence process has been determined from the Stark shift both for LE fluorescence and for exciplex fluorescence.
机译:基于对荧光光谱的场效应的测量,已经在聚合物膜中检查了菲和N,N-二甲基苯胺的亚甲基连接化合物的光诱导电子转移过程的电场效应。取决于亚甲基链的长度,电场(F)会增强分子内和分子间电子转移过程,菲发色团的局部激发态发出的LE荧光会被F淬灭。激基荧光也受F影响根据LE荧光和激基复合物荧光的Stark位移确定了荧光过程后分子极化率的变化幅度。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号