Influence of Sequential Solvation on Metal-to-Ligand Charge Transfer in Bis(2,2',2'-terpyridyl)iron(Ⅱ) Clustered with Dimethyl Sulfoxide

Thomas G. Spence; Brett T. Trotter; Lynmarie A. Posey

首页> 外文期刊>The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory >Influence of Sequential Solvation on Metal-to-Ligand Charge Transfer in Bis(2,2',2'-terpyridyl)iron(Ⅱ) Clustered with Dimethyl Sulfoxide

【24h】

Influence of Sequential Solvation on Metal-to-Ligand Charge Transfer in Bis(2,2',2'-terpyridyl)iron(Ⅱ) Clustered with Dimethyl Sulfoxide

机译：顺序溶剂化对二甲基亚砜成簇的双（2,2'，2“-吡啶基）铁（Ⅱ）中金属到配体电荷转移的影响

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The first direct measurements of the contributions of individual solvent molecules to solvent reorganization associated with photoinitiated charge transfer in a coordination complex are reported for gas-phase clusters of bis(2,2',2"-terpyridyl)iron(II), [Fe(terpy)↓(2)]↑(2+), with dimethyl sulfoxide (DMSO) prepared by electrospray ionization. Excitation of [Fe(terpy)↓(2)·(DMSO)↓(n)]↑(2+) clusters at wavelengths corresponding to the metal-to-ligand charge-transfer (MLCT) absorption characteristic of Fe(Ⅱ)-polypyridine complexes in solution triggers evaporation of solvent molecules, permitting the application of laser photofragmentation mass spectrometry to monitor MLCT absorption. The energy of the optical transition corresponding to MLCT E↓(op) is reported for [Fe(terpy)↓(2)·(DMSO)↓(n)]↑(2+) clusters (n = 1-11), and the cluster-size dependence of E↓(op) is examined following Jortner's cluster-size-equation approach (Jortner, J. Z. Phys. D 1992, 24, 247). The first 11 DMSO molecules contribute 54-63% of the bulk solvent reorganization energy, based on estimates that E↓(op) for the gas-phase [Fe(terpy)↓(2)]↑(2+) complex falls between 1.860 × 10↑(4) and 1.876 × 10↑(4) cm↑(-1).

机译：据报道，对于双（2,2'，2“-吡啶基）铁（II），[Fe]的气相簇，首次直接测量了单个溶剂分子对与配位络合物中光引发的电荷转移相关的溶剂重组的贡献的直接测量。（terpy）↓（2）]↑（2+），用电喷雾电离制备的二甲基亚砜（DMSO）激发[Fe（terpy）↓（2）·（DMSO）↓（n）]↑（2+）溶液中对应于Fe（Ⅱ）-聚吡啶配合物的金属-配体电荷转移（MLCT）吸收特征的波长的团簇触发了溶剂分子的蒸发，从而允许使用激光碎裂质谱技术监测MLCT的吸收。报告了[Fe（terpy）↓（2）·（DMSO）↓（n）]↑（2+）簇（n = 1-11）对应于MLCT E↓（op）的光学跃迁遵循Jortner的簇大小方程法（Jortner，JZ Phys。D 1992，24，247）检查E↓（op）的大小依赖性。基于气相[Fe（terpy）↓（2）]↑（2+）络合物的E↓（op）介于1.860×10↑（4）的估计，核糖占整体溶剂重组能量的54-63％）和1.876×10↑（4）cm↑（-1）。

著录项

来源
《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |1998年第40期|共8页
作者
Thomas G. Spence; Brett T. Trotter; Lynmarie A. Posey;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词

相似文献

外文文献
中文文献
专利

1. Influence of Sequential Solvation on Metal-to-Ligand Charge Transfer in Bis(2,2',2"-terpyridyl)iron(Ⅱ) Clustered with Dimethyl Sulfoxide [J] . Thomas G. Spence, Brett T. Trotter, Lynmarie A. Posey The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 1998,第37a40期

机译：顺序溶剂化对二甲基亚砜成簇的双（2,2'，2“-吡啶基）铁（Ⅱ）中金属到配体电荷转移的影响
2. Acid/base sensitive platinum terpyridyl complex: Switching between metal-to-ligand charge transfer (MLCT), ligand-to-ligand charge transfer (LLCT), and intraligand charge transfer (ILCT) states [J] . Ji ZQ, Li YJ, Sun WF Journal of Organometallic Chemistry . 2009,第26期

机译：对酸/碱敏感的铂对吡啶基络合物：在金属到配体电荷转移（MLCT），配体到配体电荷转移（LLCT）和配体内电荷转移（ILCT）状态之间切换
3. Switching between ligand-to-ligand charge-transfer, intraligand charge-transfer, and metal-to-ligand charge-transfer excited states in platinum(II) terpyridyl acetylide complexes induced by pH change and metal ions [J] . Han X, Wu LZ, Si G, Chemistry: A European journal . 2007,第26期

机译：pH值变化和金属离子诱导的铂（II）吡啶基乙炔化物络合物在配体到配体的电荷转移，配体内的电荷转移和金属到配体的电荷转移激发态之间切换
4. Intramolecular energy transfer and excitation coupling in metal-to-ligand charge transfer (MLCT) excited states [C] . Hans Riesen, Australian National Univ., Canberra, International Conference on Excitonic Processes in Condensed Matter . 1995

机译：金属到配体电荷转移（MLCT）激发态下的分子内能量转移和激发耦合
5. Towards the use of Adaptive Feedback Control Pulse Shaping to Probe and Control Reactivity of the Metal-to-Ligand Charge Transfer Excited State in Ruthenium(II) Bis-Terpyridine Complexes. [D] . Hewitt, Joshua Thomas. 2013

机译：致力于使用自适应反馈控制脉冲整形来探测和控制钌（II）双-三联吡啶配合物中金属到配体电荷转移激发态的反应性。
6. Crystal structure of bis(bis{μ3-3-methyl-3-(4-nitro-2-oxidobenzylidene)aminopropane-13-diolato}trischlorido(dimethyl sulfoxide)iron(III)) dimethyl sulfoxide heptasolvate dihydrate [O] . Eduard Chygorin, Yuri Smal, Irina V. Omelchenko 2016

机译：双（双{μ3-3-甲基-3-（4-硝基-2-氧化苄叉基）氨基丙烷-13-二醇基}三氯代（二甲基亚砜）铁（III））二甲基亚砜的晶体结构二水七溶剂化物
7. cis-Bis(2,2′-bipyridine-κ2 N,N′)bis(dimethyl sulfoxide-κO)zinc bis(tetraphenylborate) dimethyl sulfoxide monosolvate [O] . Tomyn, Stefania, Gumienna-Kontecka, Elżbieta, Usenko, Natalia I., 2011

机译：顺式双（2,2'-联吡啶-κ2 N，N'）双（二甲基亚砜-κO）双（四苯基硼酸酯）二甲亚砜单溶剂化物

Influence of Sequential Solvation on Metal-to-Ligand Charge Transfer in Bis(2,2',2'-terpyridyl)iron(Ⅱ) Clustered with Dimethyl Sulfoxide

摘要

著录项

相似文献

相关主题

期刊订阅