Vibrational Relaxation and Hydrogen-Bond Dynamics of HDO:H_2O

Michel F. Kropman; Han-Kwang Nienhuya; Sander Woutersen; Huib J. Bakker

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Vibrational Relaxation and Hydrogen-Bond Dynamics of HDO:H_2O

机译：HDO：H_2O的振动弛豫和氢键动力学

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Femtosecond two-color mid-infrared pump-probe spectroscopy is used to study the vibrational relaxationand the hydrogen-bond dynamics of HDO dissolved inliquid H_2O. By looking at the spectral dynamics of the OD stretch mode, direct information on the hydrogen-bond dynamics of the H_2O solvent is obtained. By fitting the data using the Brownian oscillator model, we determined the vibrational lifetime of the OD stretch vibrationand the hydrogen-bond length correlation time. The hydrogen-bond correlation time of H_2O is significantly shorter than for D_2O, found previosly.

机译：飞秒双色中红外泵浦探针光谱法研究了溶解在液态H_2O中的HDO的振动弛豫和氢键动力学。通过查看OD拉伸模式的光谱动力学，可以获得有关H_2O溶剂氢键动力学的直接信息。通过使用布朗振荡器模型拟合数据，我们确定了OD拉伸振动的振动寿命和氢键长度相关时间。 H_2O的氢键相关时间明显短于D_2O。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2001年第19期|共5页
作者
Michel F. Kropman; Han-Kwang Nienhuya; Sander Woutersen; Huib J. Bakker;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
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1. Vibrational Relaxation and Hydrogen-Bond Dynamics of HDO:H_2O [J] . Michel F. Kropman, Han-Kwang Nienhuya, Sander Woutersen, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2001,第19期

机译：HDO：H_2O的振动弛豫和氢键动力学
2. Vibrational Spectra and Structure of CH_3Cl:H_2O,CH_3Cl:HDO,and CH_3Cl:D_2O Complexes.IR Matrix Isolation and ab initio Calculations [J] . Nadia Dozova, Lahouari Krim, M.Esmail Alikhani, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2005,第45期

机译：CH_3Cl：H_2O，CH_3Cl：HDO和CH_3Cl：D_2O配合物的振动光谱和结构。红外矩阵分离和从头算
3. Relaxation of H_2O from its |04 ~- vibrational state in collisions with H_2O,Ar,H_2,N_2,and O_2 [J] . Peter W.Barnes, Ian R.Sims, Ian W.M.Smith The Journal of Chemical Physics . 2004,第12期

机译：与H_2O，Ar，H_2，N_2和O_2碰撞时H_2O从| 04>〜-振动状态的弛豫
4. Computer Simulation Study on the Reorientational Dynamics of HDO in H_2O [C] . Guocai Tian, Jian Li, Yixin Hua World Congress on Engineering and Computer Science . 2009

机译：H_2O中HDO重新定位动态的计算机仿真研究
5. On Ultrafast Time-Domain TeraHertz Spectroscopy in the Condensed Phase: Linear Spectroscopic Measurements of Hydrogen-Bond Dynamics of Astrochemical Ice Analogs and Nonlinear TeraHertz Kerr Effect Measurements of Vibrational Quantum Beats [D] . Allodi, Marco A. 2015

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6. Coincident Correlation between Vibrational Dynamics and Primary Relaxation of Polymers with Strong or Weak Johari-Goldstein Relaxation [O] . Antonio Tripodo, Francesco Puosi, Marco Malvaldi, 2020

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7. Vibrational Relaxation and Hydrogen-Bond Dynamics of HDO:H2O [O] . Michel F. Kropman, Han-kwang Nienhuys, Er Woutersen, 2001

机译：HDO：H2O的振动弛豫和氢键动力学
8. Electronic Bottleneck and Coherent Vibrational Effect on Relaxation Dynamics of Photoexcited Ions in Crystals [R] . Alfano, R. R. , Wang, W. B. , Liu, C. H. , 2000

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Vibrational Relaxation and Hydrogen-Bond Dynamics of HDO:H_2O

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