A Spectroscopic and Theoretical Investigation of Charge Transfer Complexese between Silver and Nitric Oxide: Infrared Spectra and Density Functional Calculations of AgNO~(+, O, -) and Ag_x(NO)_y Cluster (x, y = 1,2) in Solid Argon and Neon

Angeli Citra; Lester Andrews

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A Spectroscopic and Theoretical Investigation of Charge Transfer Complexese between Silver and Nitric Oxide: Infrared Spectra and Density Functional Calculations of AgNO~(+, O, -) and Ag_x(NO)_y Cluster (x, y = 1,2) in Solid Argon and Neon

机译：银与一氧化氮之间电荷转移配合物的光谱和理论研究：固体氩气中AgNO〜（+，O，-）和Ag_x（NO）_y团簇（x，y = 1,2）的红外光谱和密度泛函计算和霓虹灯

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Laser-ablated silver atoms are reacted with nitric oxide, and products are isolated in solid argon and neon. The pesudo-hyponitrite complex Ag(NO)_2Ag is the dominant product, with AgNOAg and AgONNO present in smaller yields. These complexes are shown using density functional theory to include signficant charge transfer from silver but are not as ionic as the analolgous alkali metal complexes of nitric oxide. The neutral and ionic mononitrosyls AgNO~+, AgNO, and AgNO~- are also observed, and qualitative trends in bond lengths and frequencies in this series are discussed.

机译：激光烧蚀的银原子与一氧化氮反应，产物被分离成固体氩气和氖气。假亚闪石络合物Ag（NO）_2Ag是主要产物，其中AgNOAg和AgONNO的收率较低。使用密度泛函理论显示这些络合物包括从银转移的重要电荷，但不像一氧化氮的芳族碱金属络合物那样具有离子性。还观察到中性和离子性的亚硝酰基AgNO〜+，AgNO和AgNO〜-，并讨论了该系列中键长和频率的定性趋势。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2001年第13期|共10页
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Angeli Citra; Lester Andrews;
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中图分类物理化学（理论化学）、化学物理学;
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1. A Spectroscopic and Theoretical Investigation of Charge Transfer Complexese between Silver and Nitric Oxide: Infrared Spectra and Density Functional Calculations of AgNO~(+, O, -) and Ag_x(NO)_y Cluster (x, y = 1,2) in Solid Argon and Neon [J] . Angeli Citra, Lester Andrews The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2001,第13期

机译：银与一氧化氮之间电荷转移配合物的光谱和理论研究：固体氩气中AgNO〜（+，O，-）和Ag_x（NO）_y团簇（x，y = 1,2）的红外光谱和密度泛函计算和霓虹灯
2. Reactions of Laser-Ablated Osmium and Ruthenium Atoms with Nitric Oxide in Neon and Argon. Matrix Infrared Spectra and Density Functional Calculations of Os(NO)_(1-3) Ru(NO)_(1-3), NOsO, NRuO, OsNO~(+) and RuNO~(+) [J] . Angelo Citra, Lester Andrews The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2000,第38期

机译：氖和氩中激光烧蚀的and原子和钌原子与一氧化氮的反应。 Os（NO）_（1-3）Ru（NO）_（1-3），NOsO，NRuO，OsNO〜（+）和RuNO〜（+）的矩阵红外光谱和密度泛函计算
3. Infrared spectra and theoretical calculations of lithium hydride clusters in solid hydrogen, neon, and argon [J] . Wang XF, Andrews L The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2007,第27期

机译：固态氢，氖和氩中氢化锂簇的红外光谱和理论计算
4. Theoretical investigations of open-shell systems: 1. Spectral simulation of the 2s(2)p(2) (2)D <- 2s(2)2p (2)P(o) valence transition in the boron diargon cluster, and 2. Quantum Monte Carlo calculations of boron in solid molecular hydrogen. [D] . Krumrine, Jennifer Rebecca. 2000

机译：开壳系统的理论研究：1.硼二氩簇中2s（2）p（2）（2）D <-2s（2）2p（2）P（o）价化合的光谱模拟，以及2固体分子氢中硼的量子蒙特卡罗计算。
5. Ultraviolet and Visible Spectroscopic Study on the 1:1 Charge-transfer Complex between N-Methyl-epsilon-thiocaprolactam and Iodine in Nonpolar and Polar Solvents. Infrared and Raman Spectra of the Solid Complex. [O] . Astri Rogstad, Else Augdahl, Bent Eichstedt Nielsen, 1971

机译：紫外线和可见光谱研究在非极性和极性溶剂中N-甲基ε-硫酰胺和碘与碘酰胺与碘的1：1电荷转移络合物。固体复合物的红外线和拉曼光谱。

A Spectroscopic and Theoretical Investigation of Charge Transfer Complexese between Silver and Nitric Oxide: Infrared Spectra and Density Functional Calculations of AgNO~(+, O, -) and Ag_x(NO)_y Cluster (x, y = 1,2) in Solid Argon and Neon

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