Electronic and Vibrational Structure of Copper Dibromide

Martin Lorenz; Vladimir E. Bondybey

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Electronic and Vibrational Structure of Copper Dibromide

机译：二溴化铜的电子和振动结构

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Absorption and laser-induced fluorescence spectra of copper dibromide in a solid neon matrix are reported. Similar to those for copper dichloride, electronic transitions between the low-lying so-called ligand field states states are forbidden by the u<->g rule, appear as a result of vibronic Herzberg-Teller coupling. The observed transition energies are in good agreement with the adiabatic state energies derived from a recent gas-phase photodetachment study by Wang and co-workers. The matrix study with its much higher resolution yields detailed information about the copper halide electronic states and their bibrational structures.

机译：报道了固体霓虹灯基质中二溴化铜的吸收和激光诱导的荧光光谱。类似于二氯化铜的那些，在低位的所谓配体场态之间的电子跃迁由于u-g规则而被禁止，这是由于振动Herzberg-Teller耦合而出现的。观察到的跃迁能量与王和他的同事最近进行的气相光解离研究得出的绝热态能量非常吻合。具有更高分辨率的矩阵研究可提供有关卤化铜电子态及其双分支结构的详细信息。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2002年第22期|共8页
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Martin Lorenz; Vladimir E. Bondybey;
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中图分类物理化学（理论化学）、化学物理学;
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1. Electronic and Vibrational Structure of Copper Dibromide [J] . Martin Lorenz, Vladimir E. Bondybey The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2002,第22期

机译：二溴化铜的电子和振动结构
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6. Crystal structures of (μ2-L1)dibromidodicopper(II) dibromide and poly(μ2-L1)diiodidodicopper(I)-di-μ-iodido-dicopper(I) where L1 is 258111417-hexathia-9.9(2635)-pyrazinophane [O] . Tokouré Assoumatine, Helen Stoeckli-Evans 2020

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Electronic and Vibrational Structure of Copper Dibromide

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