Raman Studies of the Solution Structure of Univalent Electrolytes in Water

Stephanie R. Dillon; Ralph C. Dougherty

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Raman Studies of the Solution Structure of Univalent Electrolytes in Water

机译：拉曼研究水中单价电解质的溶液结构

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This paper reports results of analysis of the OH stretch Raman spectra of aqueous solutions of electrolytes. Error analysis supports the view that the environment of the electrolyte in the liquid is that of a liquid crystalline hydrate. Fitting error analysis for a two-state model further suggests that the presence of the hydrated electrolyte perturbs the structure of the bulk water in the solution. This perturbation is consistent with the results of previous studies of the apparent density of water in aqueous solutions of electrolytes. The previous studies showed that electrolytes increase the hydrogen bond strength of the bulk water and thereby cause a shift in the water equilibrium, which results in a change of the apparent density of water in the solution.

机译：本文报告了电解质水溶液的OH拉伸拉曼光谱的分析结果。误差分析支持这样一种观点，即液体中电解质的环境就是液晶水合物的环境。两态模型的拟合误差分析进一步表明，水合电解质的存在会扰乱溶液中大量水的结构。这种扰动与先前对电解质水溶液中水的表观密度的研究结果一致。先前的研究表明，电解质会增加大量水的氢键强度，从而引起水平衡的变化，从而导致溶液中水的表观密度发生变化。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2002年第34期|共4页
作者
Stephanie R. Dillon; Ralph C. Dougherty;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
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1. Raman Studies of the Solution Structure of Univalent Electrolytes in Water [J] . Stephanie R. Dillon, Ralph C. Dougherty The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2002,第34期

机译：拉曼研究水中单价电解质的溶液结构
2. SFG study on potential-dependent structure of water at Pt electrode/electrolyte solution interface [J] . Hidenori Noguchi, Tsubasa Okada, Kohei Uosaki Electrochimica Acta . 2008,第23期

机译：SFG研究Pt电极/电解质溶液界面上水的电势依赖性结构
3. Raman spectroscopic study of the structure of water in aqueous solutions of amphoteric polymers [J] . Kitano H, Takaha K, Gemmei-Ide M Physical chemistry chemical physics: PCCP . 2006,第10期

机译：两性聚合物水溶液中水结构的拉曼光谱研究
4. In situ X-Ray absorption fine structure and raman studies of embedded lithiated manganese oxide particle electrodes in electrolyte solutions of relevance to battry applications [C] . Dana A. Totir, Daniel A. Scherson International Workshop on Electrochemical Systems . 2001

机译：原位X射线吸收细结构和嵌入式锂化锰氧化物粒子电极的嵌入式氧化锂氧化物颗粒电极与Battry应用的相关性
5. Raman and nuclear magnetic resonance spectroscopic investigations of water structure in aqueous univalent electrolyte solutions. [D] . Dillon, Stephanie Rene. 2002

机译：拉曼和核磁共振光谱研究单价电解质水溶液中的水结构。
6. Electrolyte and Plasma Changes After Ingestion of Pickle Juice Water and a Common Carbohydrate-Electrolyte Solution [O] . Kevin C. Miller, Gary Mack, Kenneth L. Knight 2009

机译：摄入泡菜汁水和普通的碳水化合物-电解质溶液后电解质和血浆的变化
7. THE STRUCTURE OF THE COLLODION MEMBRANE AND ITS ELECTRICAL BEHAVIOR : IX. WATER UPTAKE AND SWELLING OF COLLODION MEMBRANES IN AQUEOUS SOLUTIONS OF ORGANIC ELECTROLYTES AND NON-ELECTROLYTES [O] . Sollner, Karl, Beck, Paul W. 1944

机译：皱褶膜的结构及其电学行为：IX。有机电解质和非电解质水溶液中的水吸收和胶体膜溶胀
8. Raman and Infrared Spectroscopic Studies of the Structure of Water (H Sub 2 O, HOD, D sub 2 O) in Stoichiometric Crystalline Hydrates and in Electrolyte Solutions [R] . Buanam-Om, C. 1981

机译：拉曼和红外光谱研究水（H sub 2 O，HOD，D sub 2 O）在化学计量结晶水合物和电解质溶液中的结构

Raman Studies of the Solution Structure of Univalent Electrolytes in Water

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