The Ionization Potential of Si_2 N and Si_2O

S. J. Paukstis; J. L. Gole; David A. Dixon; Kirk A. Peterson

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The Ionization Potential of Si_2 N and Si_2O

机译：Si_2N和Si_2O的电离势

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One-color resonant and nonresonant ionization studies of Si_2N and Si_2O have been performed using a pulsed laser vaporization cluster source in conjunction with a time-of-flight mass spectrometer. The ionization potential of Si_2N is established as less than 6.4 eV, while the ionization potential of Si_2O is bracketed between 6.4 and 7.9 eV. The experimentally established ionization potential for Si_2N is confirmed by detailed molecular electronic structure calculations which indicate an adiabatic as well as vertical ionization potential of 6.2 ± 0.05 eV and a close similarity between neutral Si_2N and ionic Si_2N~+. Similar detailed calculations lead to a best estimate of an adiabatic ionization energy of 7.42 ± 0.04 eV and a vertical ionization energy of 7.66 ± 0.04 eV for Si_2O.

机译：已经使用脉冲激光汽化簇源结合飞行时间质谱仪对Si_2N和Si_2O进行了单色共振和非共振电离研究。 Si_2N的电离电势被确定为小于6.4 eV，而Si_2O的电离电势被包围在6.4和7.9 eV之间。通过详细的分子电子结构计算证实了实验确定的Si_2N的电离电势，该计算表明绝热和垂直电离电势为6.2±0.05 eV，并且中性Si_2N与离子型Si_2N〜+相似。类似的详细计算可得出Si_2O的绝热电离能为7.42±0.04 eV，垂直电离能为7.66±0.04 eV的最佳估计。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2002年第36期|共7页
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S. J. Paukstis; J. L. Gole; David A. Dixon; Kirk A. Peterson;
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中图分类物理化学（理论化学）、化学物理学;
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1. The Ionization Potential of Si_2 N and Si_2O [J] . S. J. Paukstis, J. L. Gole, David A. Dixon, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2002,第36期

机译：Si_2N和Si_2O的电离势
2. An estimation of the ionization potentials of actinides from a simple dependence of the aqueous standard potentials on the ionization potentials of elements including lanthanides [J] . R. Heyrovska Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2001,第0期

机译：从the水标准电势对包括镧系元素在内的元素的电离电势的简单依赖关系来估算act系元素的电离电势
3. An estimation of the ionization potentials of actinides from a simple dependence of the aqueous standard potentials on the ionization potentials of elements including lanthanides [J] . Heyrovska R. Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2001,第0期

机译：从the水标准电势对包括镧系元素在内的元素的电离电势的简单依赖关系来估算act系元素的电离电势
4. Total ionization cross-sections for Si_2, SiC, SiC_2 and Si_2C molecules [C] . C.V.Pandya ICPEAC . 2014

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5. Relationships between gas-phase ionization energies and solution-phase oxidation potentials: Applications to the electrocatalytic production of hydrogen from weak acids. [D] . Sakamoto, Takahiro. 2010

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6. Energy Relationships and Ionization Potentials of Atoms of the First Row of the Periodic Table in All Stages of Ionization [O] . R. A. Millikan, I. S. Bowen 1927

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7. Relativistic coupled-cluster studies of ionization potentials, lifetimes, and polarizabilities in singly ionized calcium [O] . Sahoo, B. K., Das, B. P., Mukherjee, D. 2009

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8. Optimum Conditions for the Determination of Ionization Potentials, Appearance Potentials, and Fine Structure in Ionization Efficiency Curves Using Edd Technique [R] . Selim, E. T., El-Kholy, S. B., Zahran, N. F. 1978

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The Ionization Potential of Si_2 N and Si_2O

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