Dynamics Study of the OH + O_2 Branching Atmospheric Reaction. 4. Influence of Vibrational Relaxation in Collisions Involving Highly Excited Species

J. D. Garrido; P. J. S. B. Caridade; A. J. C. Varandas

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Dynamics Study of the OH + O_2 Branching Atmospheric Reaction. 4. Influence of Vibrational Relaxation in Collisions Involving Highly Excited Species

机译：OH + O_2支化大气反应的动力学研究。 4.振动弛豫对高激发物种碰撞的影响

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The vibrational relaxation processes occurring during collisions of vibrationally excited O_2 and OH are investigated using the quasiclassical trajectory method and a realistic double many-body expansion (DMBE I) potential energy surface for ground-state HO_3. A salient feature is the observation of multiquanta deactivation potential energy surface for ground-state HO_3. A salient feature is the observation of colliding molecules is far less important than the reactive processes leading to formation of "odd-oxygen" (and hence ozone) under stratospheric local thermodynamic disequilibrium conditions.

机译：使用准经典轨迹方法和基态HO_3的实际双多体展开（DMBE I）势能面，研究了在振动激发的O_2和OH碰撞期间发生的振动弛豫过程。一个显着特征是观察到基态HO_3的多量子失活势能面。一个显着的特征是，在平流层局部热力学不平衡条件下，观察碰撞分子远不如导致“奇数氧”（因此形成臭氧）的反应过程重要。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2002年第21期|共9页
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J. D. Garrido; P. J. S. B. Caridade; A. J. C. Varandas;
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中图分类物理化学（理论化学）、化学物理学;
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1. Dynamics Study of the OH + O_2 Branching Atmospheric Reaction. 4. Influence of Vibrational Relaxation in Collisions Involving Highly Excited Species [J] . J. D. Garrido, P. J. S. B. Caridade, A. J. C. Varandas The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2002,第21期

机译：OH + O_2支化大气反应的动力学研究。 4.振动弛豫对高激发物种碰撞的影响
2. Dynamics Study of the O_2 + HO_2 Atmospheric Reaction with Both Reactants Highly Vibrationally Excited [J] . L. Zhang, A. J. C. Varandas The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2002,第49期

机译：高振动激发两种反应物在O_2 + HO_2大气反应中的动力学研究
3. Dynamics Study of the OH + O_2 Branching Atmospheric Reaction. 2. Influence of Reactants Internal Energy in HO_2 and O_3 Formation [J] . P.J.S.B.Caridade, L.Zhang, J.D.Garrido, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2001,第18期

机译：OH + O_2支化大气反应的动力学研究。 2.反应物内能对HO_2和O_3形成的影响
4. INFLUENCE OF THE VIBRATIONAL DISSOCIATION MODEL ON THE RELAXATION OF THE EXCITED STATES CALCULATED WITH THE CORIA'S COLLISIONAL-RADIATIVE MODEL CORAM-AIR [C] . Arnaud Bultel, Julien Annaloro, Ioan F. Schneider, Proceedings of the 7th European symposium on aerothermodynamics. . 2011

机译：振动解离模型对科里亚碰撞-辐射模型坐标-空气计算激发态弛豫的影响
5. Collision-induced vibration relaxation of highly vibrationally excited molecules. [D] . Zhang, Min. 2007

机译：碰撞引起的高振动激发分子的振动弛豫。
6. The Study of Dynamical Potentials of Highly Excited Vibrational States of HOBr [O] . Aixing Wang, Lifeng Sun, Chao Fang, 2013

机译：HOBr高激发振动态动力学势的研究
7. Dynamics Study of the OH + O2 Branching Atmospheric Reaction. 4. Influence of Vibrational Relaxation in Collisions Involving Highly Excited Species [O] . 2015

机译：OH + O2支化大气反应动力学研究。 4.振动弛豫对高激发态碰撞的影响
8. Vibrational Relaxation of Highly Excited Diatomics. V. The V-V Channel in HF(v)+HF(O) Collisions [R] . Dzelzkalns, L. S., Kaufman, F. 1983

机译：高激发硅原子的振动弛豫。 V. HF（v）+ HF（O）碰撞中的V-V通道

Dynamics Study of the OH + O_2 Branching Atmospheric Reaction. 4. Influence of Vibrational Relaxation in Collisions Involving Highly Excited Species

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