The Reaction of HCCO + O_2: Experimental Evidence of Prompt CO_2 by Time-Resolved Fourier Transform Spectroscopy

David L. Osborn

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The Reaction of HCCO + O_2: Experimental Evidence of Prompt CO_2 by Time-Resolved Fourier Transform Spectroscopy

机译：HCCO + O_2的反应：时间分辨傅立叶变换光谱法提示CO_2的实验证据

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The products CO and CO_2 are observed experimentally for the first time in the HCCO + O_2 reaction. Both product molecules have identical appearance times and are formed simultaneously rather than sequentially. Both CO and CO_2 are produced with significant internal excitation. The product channel producing H + CO + CO_2 accounts for at least 90% of the reaction products at 298 K. The results explain the observation of "prompt" CO_2 in acetylene oxidation chemistry.

机译：在HCCO + O_2反应中首次通过实验观察到了产物CO和CO_2。两种产物分子具有相同的出现时间，并且同时而不是顺序形成。 CO和CO_2都是通过明显的内部激发产生的。在298 K时，生成H + CO + CO_2的产物通道至少占反应产物的90％。结果解释了在乙炔氧化化学中观察到“迅速” CO_2的现象。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2003年第19期|共5页
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David L. Osborn;
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中图分类物理化学（理论化学）、化学物理学;
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1. The Reaction of HCCO + O_2: Experimental Evidence of Prompt CO_2 by Time-Resolved Fourier Transform Spectroscopy [J] . David L. Osborn The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2003,第19期

机译：HCCO + O_2的反应：时间分辨傅立叶变换光谱法提示CO_2的实验证据
2. Time-Resolved Fourier Transform Infrared Spectroscopy of Chemical Reactions in Solution Using a Focal Plane Array Detector [J] . N. KAUN, M. J. VELLEKOOP, B. LENDL Applied Spectroscopy: Society for Applied Spectroscopy . 2006,第11期

机译：使用焦平面阵列检测器的溶液中化学反应的时间分辨傅里叶变换红外光谱
3. FAST TIME-RESOLVED FOURIER-TRANSFORM SPECTROSCOPY FOR THE STUDY OF TRANSIENT CHEMICAL REACTIONS [J] . Carere CA., Sloan JJ., Neil WS. Applied optics . 1996,第16期

机译：研究瞬态化学反应的快速时间分辨傅里叶变换光谱
4. RESOLVING THE MYSTERY OF PROMPT CO_2: THE HCCO + O_2 REACTION [C] . STEPHEN J. KLIPPENSTEIN, JAMES A. MILLER, LAWRENCE B. HARDING Twenty-Ninth International Symposium on Combustion Hokkaido University . 2002

机译：解决瞬发CO_2的奥秘：HCCO + O_2反应
5. Application of time-resolved Fourier-transform infrared spectroscopy to studies of the photochemistry of alkyl phenylglyoxylates. [D] . Merzlikine, Alexei G. 2003

机译：时间分辨傅立叶变换红外光谱在烷基苯乙醛酸酯光化学研究中的应用。
6. Experimental evidence for hydrogen-bonded network proton transfer in bacteriorhodopsin shown by Fourier-transform infrared spectroscopy using azide as catalyst. [O] . J Le Coutre, J Tittor, D Oesterhelt, 1995

机译：使用叠氮化物作为催化剂的傅里叶变换红外光谱显示了细菌视紫红质中氢键网络质子转移的实验证据。
7. The reaction of CH2(B-3(1))+N2O studied by time-resolved Fourier transform infrared spectroscopy [O] . Su HM, Yang JX, Zhong JX, 1999

机译：时间分辨傅里叶变换红外光谱研究CH2（B-3（1））+ N2O的反应
8. Time-Resolved FTIR (Fourier Transform) Emission Studies of Laser Photofragmentation and Chain Reactions: Progress Report, April 1, 1988-March 31, 1989 [R] . Leone, S. R. 1988

机译：时间分辨FTIR（傅里叶变换）激光光致碎裂和链式反应的发射研究：进展报告，1988年4月1日 - 1989年3月31日

The Reaction of HCCO + O_2: Experimental Evidence of Prompt CO_2 by Time-Resolved Fourier Transform Spectroscopy

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