Thermal Rate Constant for CN + H_2/D_2 → HCN/DCN + H/D Reaction from T = 293 to 380 K

G. He; I. Tokue; R. Glen Macdonald

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Thermal Rate Constant for CN + H_2/D_2 → HCN/DCN + H/D Reaction from T = 293 to 380 K

机译：T = 293至380 K时CN + H_2 / D_2→HCN / DCN + H / D反应的热速率常数

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The reaction rate constant for the cyano (CN) radical with hydrogen and deuterium has been determined over the temperature range 293-380 K. The CN radical was detected by time-resolved near-infrared absorption using the CN red system (A~2II ← X~2∑) (2, 0) band near 790 nm. These measurements were carried out at low pressures of Ar or He as carrier gas. The diffusion rate of CN in these mixtures was inferred from the diffusion rate of HCN(000) determined using time-resolved infrared absorption of HCN(000) around 3.0 μm, simultaneously with the detection of CN. These measurements provide accurate thermal rate constant data that will enable a detailed comparison to be made between theoretical predictions and experimental measurements for this prototypical reaction system.

机译：在293-380 K的温度范围内，测定了氰基（CN）与氢和氘的反应速率常数。使用CN红体系通过时间分辨近红外吸收法检测CN自由基（A〜2II← X〜2∑）（2，0）波段接近790 nm。这些测量是在作为载气的氩气或氦气的低压下进行的。从HCN（000）的扩散速率可以推断出CN在这些混合物中的扩散速率，而HCN（000）的扩散速率是通过HCN（000）在3.0μm左右的时间分辨红外吸收测定的，同时检测CN。这些测量可提供准确的热速率常数数据，从而可以对该原型反应系统进行理论预测和实验测量之间的详细比较。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |1998年第24期|共7页
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G. He; I. Tokue; R. Glen Macdonald;
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中图分类物理化学（理论化学）、化学物理学;
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1. Thermal Rate Constant for CN + H_2/D_2 → HCN/DCN + H/D Reaction from T = 293 to 380 K [J] . G. He, I. Tokue, R. Glen Macdonald The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 1998,第24期

机译：T = 293至380 K时CN + H_2 / D_2→HCN / DCN + H / D反应的热速率常数
2. Thermal Rate Constant and Branching Ratio for CN + HD → HCN/DCN + D/H from T = 293 to 375 K [J] . G. He, I. Tokue, Lawrence B. Harding The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 1998,第37a40期

机译：CN + HD→HCN / DCN + D / H的热速率常数和分支比从T = 293到375 K
3. State-to-state and total rotational energy transfer rate constants for N(B~2#SIGMA#~+, v=0,N)+H_2, CN(X~2#SIGMA#~+,v=2,N)+H_2, D_2, and CN(X~2#SIGMA#~+,v=3,N)+NO [J] . Sophie M. D. Brunet, Jingzhong Guo, Tucker Carrington, The Journal of Chemical Physics . 2002,第9期

机译：N（B〜2＃SIGMA＃〜+，v = 0，N）+ H_2，CN（X〜2＃SIGMA＃〜+，v = 2，N）的状态对状态和总旋转能量传输速率常数+ H_2，D_2和CN（X〜2＃SIGMA＃〜+，v = 3，N）+ NO
4. Isotope mixing in plasmas of H_2 and D_2 by ion processes and wall reactions [C] . I. Tanarro, V. J. Herrero International conference on phenomena in ionized gases;ICPIG 2009 . 2009

机译：通过离子过程和壁反应在H_2和D_2等离子体中进行同位素混合
5. Semiclassical and Quantum Instanton approximations for thermal rate constants of chemical reactions. [D] . Ceotto, Michele. 2005

机译：化学反应热速率常数的半经典和量子Instanton近似。
6. Rates and equilibrium constants of the ligand-induced conformationaltransition of an HCN ion channel protein domain determined by DEERspectroscopy [O] . Alberto Collauto, Hannah A. DeBerg, Royi Kaufmann, -1

机译：配体诱导的构象的速率和平衡常数DEER确定的HCN离子通道蛋白结构域的过渡光谱学
7. On the Rate Constant for the Association Reaction H + CN + Ar → HCN + Ar [O] . Rodrigues S. P. J., Varandas A. J. C. 1999

机译：缔合反应H + CN + Ar→HCN + Ar的速率常数
8. Interaction of HCN(DCN) with Si(111)-7x7 Studied with HREELS, UPS and XPS [R] . Bu, Y., Ma, L., Lin, M. C. 1993

机译：HCN（DCN）与si（111）-7x7的相互作用用HREELs，Ups和Xps研究

Thermal Rate Constant for CN + H_2/D_2 → HCN/DCN + H/D Reaction from T = 293 to 380 K

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