Dependence of Calculated Product Rotational Polarizations on the Scattering Angle for the O(~1D) + HCl Reaction

J. M. Alvarino; A. Bolloni; M. L. Hernandez; A. Lagana

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Dependence of Calculated Product Rotational Polarizations on the Scattering Angle for the O(~1D) + HCl Reaction

机译：O（〜1D）+ HCl反应的产物旋转极化对散射角的依赖性

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To investigate the effect of the structure of the potential energy surface on the vector properties of the O(~1D) + HCl reaction, we carried out a quasiclassical trajectory study of some two and three vector correlations. The analysis of the allocation of the angular momentum and of the variation with the scattering angle of the second Legendre moment related to the distribution of the product rotational angular momentum with respect to relative velocity indicated that the formation of an intermediate complex is responsible for deviations from the kinematic limiting behavior. The complex formation explains also the agreement of trajectory results with those of a statistical model reaction proposed by Herschbach (Case, D. A.; Herschbach, D. R. Mol. Phys. 1975, 30, 1537).

机译：为了研究势能表面的结构对O（〜1D）+ HCl反应的矢量性质的影响，我们对大约两个和三个矢量相关性进行了准经典轨迹研究。对角动量的分配以及第二勒让德矩的散射角随产品旋转角动量相对于相对速度的分布的变化的变化的分析表明，中间复合物的形成是导致与运动极限行为。络合物的形成还解释了轨迹结果与赫希巴赫提出的统计模型反应的轨迹的一致性（Case，D.A。; Herschbach，D.R.Mol.Phys.1975，30，1537）。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |1998年第50期|共5页
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J. M. Alvarino; A. Bolloni; M. L. Hernandez; A. Lagana;
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中图分类物理化学（理论化学）、化学物理学;
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1. Dependence of Calculated Product Rotational Polarizations on the Scattering Angle for the O(~1D) + HCl Reaction [J] . J. M. Alvarino, A. Bolloni, M. L. Hernandez, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 1998,第50期

机译：O（〜1D）+ HCl反应的产物旋转极化对散射角的依赖性
2. Product Rotational Polarization in Photo-initiated Bimolecular Reactions A + BC: Dependence on the Character of the Potential Energy Surface for Different Mass Combinations [J] . Ming-Liang Wang, Ke-Li Han, Guo-Zhong He The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 1998,第50期

机译：光引发的双分子反应A + BC中的产物旋转极化：取决于不同质量组合的势能面的特征
3. Theoretical prediction of energy dependence for D + BrO → DBr + O reaction: The rate constant and product rotational polarization [J] . Zhang Ying-Ying, Xie Ting-Xian, Li Ze-Rui, 中国物理：英文版 . 2015,第003期

机译：D + BrO→DBr + O反应的能量依赖性的理论预测：速率常数和产物旋转极化
4. Effect of Reagent Vibrational Excitation on Product Rotational Polarization in Reactions Li + DF (v=0-3, j=0)→ LiF(v', j') + D [C] . Jie Cheng, Xian-Fang Yue International Conference on Chemical Engineering and Advanced Materials . 2013

机译：试剂振动激发对反应中产物旋转极化的影响Li + DF（V = 0-3，J = 0）→LiF（V'，J'）+ D.
5. CROSSED MOLECULAR BEAM STUDY OF THE REACTIVE SCATTERING OF POTASSIUM PLUSIODINE: PRODUCT POTASSIUM-IODIDE RECOIL (VELOCITY-ANGLE) DISTRIBUTIONS AND ENERGY DEPENDENCE OF REACTION CROSS-SECTION. [D] . GILLEN, KEITH THOMAS. 1970

机译：钾正碘反应性散射的交叉分子束研究：碘化钾产物的回弹（速度角）分布和反应截面的能量依赖性。
6. The dynamical study of O(1D) + HCl(v = 0 j = 0) reaction at hyperthermal collision energies [O] . Meihua Ge, Huan Yang, Yujun Zheng 2013

机译：O（1D）+ HCl（v = 0j = 0）在高温碰撞能量下的动力学研究
7. Influence of collision energy and reagent rotation on the cross sections and product polarizations of the reaction F plus HCl [O] . Duan Zhi Xin, Li Wen Liang, Qiu Ming Hui 2012

机译：碰撞能量和试剂旋转对反应F加HCl的横截面和产物极化的影响

Dependence of Calculated Product Rotational Polarizations on the Scattering Angle for the O(~1D) + HCl Reaction

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