Resonance Raman Study of the Short-Time Photodissociation Dynamics of the A-Band Absorption of Cyclopropyl Iodide in Cyclohexane Solution

Xuming Zheng; Yun-Liang Li; David Lee Phillips

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Resonance Raman Study of the Short-Time Photodissociation Dynamics of the A-Band Absorption of Cyclopropyl Iodide in Cyclohexane Solution

机译：环己烷溶液中环丙基碘化物A波段吸收的短时光解离动力学的共振拉曼研究

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Resonance Raman spectra were obtained for cyclopropyl iodide in cyclohexane solution with excitation wavelengths in resonance with the A-band absorption spectrum.These spectra indicate that the Franck-Condon region photodissociation dynamics have multidimensional character with motion mainly along the nominal C-I stretch and nominal C-C-I deformation normal modes accompanied by moderate motion along the nominal cyclopropyl ring breathing and ring deformation normal modes.A preliminary resonance Raman intensity analysis was done,and the results for cyclopropyl iodide were compared to previously reported results for several cyclic and noncyclic alkyl iodides.

机译：得到了环丙基碘在环己烷溶液中的共振拉曼光谱，激发波长与A带吸收光谱共振，这些光谱表明Franck-Condon区光解离动力学具有多维特征，其运动主要沿着标称CI拉伸和标称CCI变形。正常模式伴随沿名义环丙基环呼吸的适度运动和环变形正常模式。进行了初步共振拉曼强度分析，并将环丙基碘的结果与先前报道的几种环状和非环状烷基碘的结果进行了比较。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2004年第39期|共8页
作者
Xuming Zheng; Yun-Liang Li; David Lee Phillips;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
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1. Resonance Raman Study of the Short-Time Photodissociation Dynamics of the A-Band Absorption of Cyclopropyl Iodide in Cyclohexane Solution [J] . Xuming Zheng, Yun-Liang Li, David Lee Phillips The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2004,第39期

机译：环己烷溶液中环丙基碘化物A波段吸收的短时光解离动力学的共振拉曼研究
2. A-band resonance Raman spectra of 1,2-diiodoethane in cyclohexane solution. Substituent effects on the 1-halo-2-iodoethane short-time photodissociation dynamics [J] . Zheng XM., Phillips DL., Cheng YF. Chemical Physics Letters . 1998,第3期

机译：1,2-二碘乙烷在环己烷溶液中的A带共振拉曼光谱。取代基对1-卤-2-碘乙烷短时光解离动力学的影响
3. Resonance Raman Study of Short-Time Photodissociation Dynamics of the Charge-Transfer Band Absorption of Nitrobenzene in Cyclohexane Solution [J] . Xin-Ming Zhu, Shu-Qiang Zhang, Xuming Zheng, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2005,第13期

机译：环己烷溶液中硝基苯电荷转移带吸收的短时光解离动力学的共振拉曼研究
4. Photodissociation Dynamics of Acetone in the Gas Phase and in Solution Studied by Transient Absorption and Femtosecond Stimulated Raman Spectroscopy [C] . Seung Min En, Hye Ran Koh, Ilseung Yang, International Conference on Raman Spectroscopy . 2010

机译：气相中丙酮和瞬态吸收和飞秒刺激拉曼光谱法研究了丙酮的光积极性动态
5. ULTRASONIC ABSORPTION STUDY OF EPSILON-CAPROLACTAM IN CYCLOHEXANE SOLUTIONS. [D] . EMARA, MOSTAFA MAHMOUD. 1971

机译：环己烷溶液中ε-己内酰胺的超声吸收研究。
6. Structural and dynamic properties of the homodimeric hemoglobin from Scapharca inaequivalvis Thr-72--Ile mutant: molecular dynamics simulation low temperature visible absorption spectroscopy and resonance Raman spectroscopy studies. [O] . M Falconi, A Desideri, A Cupane, 1998

机译：Scapharca inaequivalvis Thr-72- Ile突变体同型二聚体血红蛋白的结构和动力学性质：分子动力学模拟低温可见吸收光谱和共振拉曼光谱研究。
7. Resonance Raman Study of Short-Time Photodissociation Dynamics of the Charge-Transfer Band Absorption of Nitrobenzene in Cyclohexane Solution [O] . -1

机译：环己烷溶液中硝基苯的电荷转移带吸收的短时光解码动力学的共振拉曼研究

Resonance Raman Study of the Short-Time Photodissociation Dynamics of the A-Band Absorption of Cyclopropyl Iodide in Cyclohexane Solution

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