Emission Spectra of Group 13 Metal Atoms and Indium Hydrides in Solid H_2 and D_2

Xuefeng Wang; Bret Wolfe; Lester Andrews

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Emission Spectra of Group 13 Metal Atoms and Indium Hydrides in Solid H_2 and D_2

机译：固体H_2和D_2中13族金属原子和铟氢化物的发射光谱

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Infrared spectra of solid hydrogen (deuterium) samples co-deposited at 3.5 K with laser-ablated Al, Ga, In, and Tl atoms reveal infrared absorptions for the MH [MD] molecules. Irradiation at 193 nm increases MH_2 and MH_3 [MD_2 and MD_3] absorptions and produces emission spectra for the metal atoms except for Al and phosphorescence spectra for the InH [InD] molecules. Unreacted metal emission bands are blue-shifted from the gas phase more by solid D_2 than by solid H_2. However, the emission yield for InD is much higher in solid D_2 than for InH in solid H_2, which suggests a higher nonradiative relaxation rate in solid H_2 than in solid D_2 owing to the larger zero-point motion.

机译：与激光烧蚀的Al，Ga，In和Tl原子共沉积在3.5 K的固体氢（氘）样品的红外光谱揭示了MH [MD]分子的红外吸收。在193 nm处进行辐照会增加MH_2和MH_3 [MD_2和MD_3]的吸收，并产生金属原子的发射光谱（Al除外）和InH [InD]分子的磷光光谱。固态D_2比固态H_2更能使未反应的金属发射带从气相蓝移。但是，固体D_2中InD的发射产率比固体H_2中InH的发射产率高得多，这表明由于较大的零点运动，固体H_2中的非辐射弛豫速率比固体D_2中的更高。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2004年第24期|共6页
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Xuefeng Wang; Bret Wolfe; Lester Andrews;
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中图分类物理化学（理论化学）、化学物理学;
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1. Emission Spectra of Group 13 Metal Atoms and Indium Hydrides in Solid H_2 and D_2 [J] . Xuefeng Wang, Bret Wolfe, Lester Andrews The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2004,第24期

机译：固体H_2和D_2中13族金属原子和铟氢化物的发射光谱
2. Emission Spectra of Group 13 Metal Atoms and Indium Hydrides in Solid H2 and D2 [J] . Xuefeng Wang, Bret Wolfe, Lester Andrews The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2004,第24期

机译：固体H2和D2中13族金属原子和铟氢化物的发射光谱
3. Infrared Spectra and DFT Calculations for the Coinage Metal Hydrides MH, (H_2)MH, MH_2, M_2H, M_2H~-, and (H_2)CuHCu in Solid Argon, Neon, and Hydrogen [J] . Xuefeng Wang, Lester Andrews, Laurent Manceron, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2003,第41期

机译：固态氩，氖和氢中的硬币金属氢化物MH，（H_2）MH，MH_2，M_2H，M_2H〜-和（H_2）CuHCu的红外光谱和DFT计算
4. Tunneling Abstraction Reactions of Tritium Atoms with HD and with mixtures of H_2 and D_2 in Super - and Normalfluid ~He-~4He media at 1.3K [C] . Y.Aratono, T.Matsumoto, T.Takayanagi, Meeting on tunneling reaction and low temperature chemistry . 1998

机译：K原子与HD以及H_2和D_2的混合物在1.3K超和正流体〜He-〜4He介质中的隧穿抽象反应。
5. Synthesis and reaction chemistry of homonuclear metal-metal bonded group 12 (zinc, cadmium and mercury) and group 13 (gallium and indium) organometallic compounds ArMMAr (Ar = terphenyl ligands) and related species. [D] . Zhu, Zhongliang. 2009

机译：同核金属-金属键合的12族（锌，镉和汞）和13族（镓和铟）有机金属化合物ArMMAr（Ar =三联苯配体）及相关物质的合成和反应化学。
6. Resolving hydrogen atoms at metal-metal hydride interfaces [O] . Sytze de Graaf, Jamo Momand, Christoph Mitterbauer, 2020

机译：解析金属-金属氢化物界面上的氢原子
7. Isotope effect of H^-/D^- volume production in low-pressure H_2/D_2 plasmas : Measurement of VUV emissions and negative ion densities [O] . Fukumasa, O., Mori, S., Nakada, N., 2004

机译：低压H_2 / D_2等离子体中H ^-/ D ^-量产的同位素效应：VUV发射和负离子密度的测量
8. Addition Compounds of Alkali Metal Hydrides. 13. Reactions of Alkali Metal Hydrides with Trialkylboranes. Synthesis and Dissociation of Alkali Metal Trialkylborohydrides. Ethyl Ether-Organoborane as a Reversible 'Solvent' for Lithium Hydride. [R] . Brown, H. C., Khuri, A., Kim, S. C. 1977

机译：碱金属氢化物的加成化合物。 13.碱金属氢化物与三烷基硼烷的反应。碱金属三烷基硼氢化物的合成与解离。乙醚 - 有机硼烷作为氢化锂的可逆“溶剂”。

Emission Spectra of Group 13 Metal Atoms and Indium Hydrides in Solid H_2 and D_2

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