Theoretical Estimates of Redox Potentials for Group 6 Elements, Including Element 106, Seaborgium, in Acid Solutions

V. Pershina; E. Johnson; B. Fricke

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Theoretical Estimates of Redox Potentials for Group 6 Elements, Including Element 106, Seaborgium, in Acid Solutions

机译：酸性溶液中第6组元素（包括元素106，Sea）的氧化还原电位的理论估计

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Standard reduction potentials for group 6 elements, including element 106 (Sg), in acid solutions have been estimated on the basis of ionization potentials calculated using the multiconfiguration Dirac-Fock method. The stability of the 6+ oxidation state is shown to increase within group 6, while that of the 5+, 4+, and 3+ states is shown to decrease. No extra stability of the 4+ oxidation state of Sg can be inferred. Thus, no deviation from the Mendeleev-type periodicity is found for group 6 elements.

机译：基于使用多配置狄拉克-福克方法计算出的电离电势，已经估算出酸溶液中第6组元素（包括元素106（Sg））的标准还原电势。在组6中，6+氧化态的稳定性显示出增加，而5+，4+和3+态的稳定性下降。不能推断出Sg的4+氧化态的额外稳定性。因此，对于第6组元素，没有发现与门捷列夫型周期性的偏差。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |1999年第42期|共8页
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V. Pershina; E. Johnson; B. Fricke;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
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1. Theoretical Estimates of Redox Potentials for Group 6 Elements, Including Element 106, Seaborgium, in Acid Solutions [J] . V. Pershina, E. Johnson, B. Fricke The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 1999,第42期

机译：酸性溶液中第6组元素（包括元素106，Sea）的氧化还原电位的理论估计
2. Solution chemistry of element 106 :theoretical predictions of hydrolysis of group 6 cations mo,W,and Sg [J] . V.Pershina, J.V.Kratz Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2001,第4期

机译：元素106的溶液化学：6族阳离子mo，W和Sg水解的理论预测
3. Evaluation of selected static methods used to estimate element mobility, acid-generating and acid-neutralizing potentials associated with geologically diverse mining wastes [J] . Hageman Philip L., Seal Robert R., Diehl Sharon F., Applied Geochemistry: Journal of the International Association of Geochemistry and Cosmochemistry . 2015,第Null期

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4. Aqueous Redox Potentials Related to Ionization Potentials and Electron Affinities of Elements by Simple Linear Equations [C] . R.Heyrovska The Meeting of the Electrochemical Society . 2000

机译：通过简单的线性方程与元件的电离电位和电子亲戚有关的水性氧化还原电位
5. Relativistic effective core potentials and the theoretical chemistry of the transactinide elements. [D] . Nash, Clinton Scott. 1996

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7. Sorption Behaviour of Uranium on Cation and Anion Exchange Resins from HCl/HF-Containing Aqueous Solutions: Model Experiments for the Determination of Chemical Properties of Element 106 (Seaborgium) [O] . Schumann, D., Andrassys, M., Nitsche, H., 2017

机译：铀在含HCl / HF的水溶液中在阳离子和阴离子交换树脂上的吸附行为：测定元素106（b）化学性质的模型实验

Theoretical Estimates of Redox Potentials for Group 6 Elements, Including Element 106, Seaborgium, in Acid Solutions

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