Laser-Induced NMR Shift for Hg~(199) Atom

Li Li; Tianjing He; Dongming Chen; Xiuyan Wang; Fan-Chen Liu

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Laser-Induced NMR Shift for Hg~(199) Atom

机译：Hg〜（199）原子的激光诱导NMR位移

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Laser-induced NMR shifts are studied theoretically by semiclassical treatment as a dynamic Stark effects of optical fields. It is proved that light shifts in optical pumping experiment and in NMR and ESR spectra are based on the identical fundamental principle. The calculated NMR shift for a Hg~(199) atom can be of the order of 1 MHz in a circularly polarized laser beam 10 W cm~(-2) at a frequency near the singlet-triplet transition absorption.

机译：理论上，通过半经典处理将激光诱导的NMR位移作为光场的动态Stark效应进行研究。事实证明，光泵浦实验，NMR和ESR光谱中的光移均基于相同的基本原理。在接近单重态-三重态跃迁吸收的频率下，在10 W cm〜（-2）的圆偏振激光束中，计算出的Hg〜（199）原子的NMR位移约为1 MHz。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |1998年第50期|共6页
作者
Li Li; Tianjing He; Dongming Chen; Xiuyan Wang; Fan-Chen Liu;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
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1. Laser-Induced NMR Shift for Hg~(199) Atom [J] . Li Li, Tianjing He, Dongming Chen, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 1998,第50期

机译：Hg〜（199）原子的激光诱导NMR位移
2. The Application of ~(199)Hg NMR and ~(199m)Hg Perturbed Angular Correlation (PAC) Spectroscopy to Define the Biological Chemistry of Hg~(II): A Case Study with Designed Two- and Three-Stranded Coiled Coils [J] . Olga Iranzo, Peter W. Thulstrup, Seung-baek Ryu Chemistry: A European journal . 2007,第33期

机译：〜（199）Hg NMR和〜（199m）Hg扰动角相关（PAC）光谱学在确定Hg〜（II）的生物化学中的应用：以设计的二链和三链螺旋线圈为例
3. Synthesis, NMR (C-13, Cd-111 Hg-199) spectra and structures of (Ph4As)(2)[Hg2Cl4(SC(O)Ph)(2)] and (Ph4As)(2)[CdCl4Hg(SC(O)Ph)(2)] [J] . Vittal JJ., Dean PAW. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1998,第11a12期

机译：（Ph4As）（2）[Hg2Cl4（SC（O）Ph）（2）]和（Ph4As）（2）[CdCl4Hg（SC（ O）Ph）（2）]
4. EXPLORING THE OXYGEN ORDER IN Hg -1223 AND Hg -1201 BY ~(199)Hg MAS NMR [C] . Raivo Stern, Ivo Heinmaa, Dmitriy A. Pavlov, NATO Advanced Research Workshop on New Challenges in Superconductivity: Experimental Advances and Emerging Theories . 2005

机译：探索HG -1223和HG -1201中的氧气顺序〜（199）HG MAS NMR
5. Axion-Like Dark Matter Detection With Mercury-199 Atoms [D] . Chen, Yi. 2018

机译：轴状暗物质检测与水银 - 199原子
6. 13C and 199Hg nuclear magnetic resonance spectroscopic study of alkenemercurinium ions: Effect of methyl substituents on 199Hg chemical shifts [O] . George A. Olah, Armando Garcia-Luna 1980

机译：烯烃汞离子的13 C和199 Hg核磁共振光谱研究：甲基取代基对199 Hg化学位移的影响
7. 13C and 199Hg nuclear magnetic resonance spectroscopic study of alkenemercurinium ions: Effect of methyl substituents on 199Hg chemical shifts [O] . Olah, George A., Garcia-Luna, Armando 1980

机译：烯烃汞离子的13 C和199 Hg核磁共振光谱研究：甲基取代基对199 Hg化学位移的影响
8. sup 199 Hg and (sup 63,65)Cu NMR studies of mercury based high-Tc superconductors [R] . Hoffmann, W. , Breitzke, H. , Simmons, C. T. , 1994

机译：sup 199 Hg和（sup 63,65）铜基高Tc超导体的Cu NmR研究

Laser-Induced NMR Shift for Hg~(199) Atom

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