首页> 外文期刊>The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory >Spectral Autocorrelation Function in Weakly Open Chaotic Systems: Indirect Photodissociation of Molecules
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Spectral Autocorrelation Function in Weakly Open Chaotic Systems: Indirect Photodissociation of Molecules

机译:弱开放混沌系统中的光谱自相关函数:分子的间接光解离

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摘要

We derive the statistical limit of the spectral autocorrelation function and of the survival probability for the indirect photodissociation of molecules in the regime of nonoverlapping resonances. The results are derived in the framework of random matrix theory and hold more generally for any chaotic quantum system that is weakly coupled to the continuum. The "correlation hole" that characterizes the spectral autocorrelation in the bound molecule diminishes as the typical average total width of a resonance increases.
机译:我们推导了光谱自相关函数的统计极限,以及非重叠共振模式下分子间接光解离的生存概率。结果是在随机矩阵理论的框架中得出的,并且更普遍地适用于任何与连续体弱耦合的混沌量子系统。随着共振的典型平均总宽度增加,表征结合分子中光谱自相关的“相关孔”减小。

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