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Is There a Magnetic Field Effect on Electrochemical Kinetics?

机译:磁场对电化学动力学有影响吗?

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摘要

Whether the influence of magnetic field B on the diffusion process during an electrochemical reaction is now well known, the magnetic field effects on the electrochemical kinetics are still a subject of controversy. We have investigated, by means of electrochemical impedance spectroscopy, different electrochemical systems, mass transport controlled, kinetically controlled, and mixed systems, under superimposed B. All results led to the conclusion that a homogeneous B parallel to the electrode surface and varying up to 1 T had no effect on the charge-transfer coefficient.
机译:现在是否众所周知磁场B对电化学反应过程中扩散过程的影响,磁场对电化学动力学的影响仍是一个有争议的话题。我们已经通过电化学阻抗谱研究了在叠加B下的不同电化学系统,传质控制,动力学控制和混合系统。所有结果均得出结论:均质B平行于电极表面并变化至1 T对电荷转移系数没有影响。

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