Heats of Formation for Cyclic C_4F_n,,n=4-8,and Their Cations

Charles W.Bauschlicher; Alessandra Ricca

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Heats of Formation for Cyclic C_4F_n,,n=4-8,and Their Cations

机译：循环C_4F_n，n = 4-8的形成热及其阳离子

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Heats of formationfor cyclic C_4F_8 and C_4F_8~+ are determined at the G3MP2 level.The several decomposition pathways are investigated.The calculatiosn confirm that C_4F_8~+ rearranges and its decomposition is responsible for both the C_2F_4~+ and C_3F_5~+ species observed in experiment.The heats of formation are presented for C_4F_n and C_4F_n~+,n=4-8.

机译：在G3MP2水平确定了循环C_4F_8和C_4F_8〜+的形成热，研究了几种分解途径，计算证实了C_4F_8〜+重排且其分解是实验中观察到的C_2F_4〜+和C_3F_5〜+的原因。给出了C_4F_n和C_4F_n〜+，n = 4-8的形成热。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2000年第39期|共3页
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Charles W.Bauschlicher; Alessandra Ricca;
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中图分类物理化学（理论化学）、化学物理学;
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1. Heats of Formation for Cyclic C_4F_n,,n=4-8,and Their Cations [J] . Charles W.Bauschlicher, Alessandra Ricca The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2000,第39期

机译：循环C_4F_n，n = 4-8的形成热及其阳离子
2. Heats Formation for Cyclic C_4F_n, n = 4-8, and Their Cations [J] . Charles W. Bauschlicher Jr., Alessandra Ricca The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2000,第39期

机译：循环C_4F_n，n = 4-8的热形成及其阳离子
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Heats of Formation for Cyclic C_4F_n,,n=4-8,and Their Cations

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