Pt-Ru and Pt-Ru-P/Carbon Nanocomposites: Synthesis, Characterization, and Unexpected Performance as Direct Methanol Fuel Cell (DMFC) Anode Catalysts

William D. King; James D. Corn; Oliver J. Murphy; Deborah L. Boxall; Edward A. Kenik; Krzysztof C. Kwiatkowski; Stuart R. Stock; C. M. Lukehart

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Pt-Ru and Pt-Ru-P/Carbon Nanocomposites: Synthesis, Characterization, and Unexpected Performance as Direct Methanol Fuel Cell (DMFC) Anode Catalysts

机译：Pt-Ru和Pt-Ru-P /碳纳米复合材料：直接甲醇燃料电池（DMFC）阳极催化剂的合成，表征和意外性能

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Six Pt-Ru/carbon nanocomposites have been prepared, using five different Pt, Ru-bimetallic precursors as sources of metal. Nanocomposites prepared from precursors lacking phosphorus contain Pt-Ru nanocrystals that are highly dispersed on the carbon support, as expected. However, nanocomposites prepared from precursors possessing phosphorus contain a mixture of face-centered-cubic Pt-Ru alloy nanocrystals and primitivecubic nanocrystals of an interstitial ternary metal phosphide phase identified as PtRuP_2. Nanocomposites containing substantial amounts of nano-PtRuP_2 perform as well as a commercial Pt/Ru/carbon nanocomposite in the role of an anode catalyst in direct methanol fuel cells. Although the exclusion of metal phosphide phases in Pt-Ru nanocomposite syntheses is best achieved by eliminating all sources of phosphorus, the presence of Pt-Ru nanocomposite syntheses is best achieved by eliminating all sources of phosphorus, the presence of PtRuP_2 in such nanocomposites does not poison methanol electrooxidation. Investigation of the synthesis and electrocatalytic reactivity of pure PtRuE_x (where E denotes a main-group heteroelement) phases is suggested.

机译：使用五种不同的Pt Ru-双金属前驱体作为金属源，已经制备了六种Pt-Ru /碳纳米复合材料。如所预期的那样，由缺乏磷的前体制备的纳米复合材料包含高度分散在碳载体上的Pt-Ru纳米晶体。然而，由具有磷的前体制备的纳米复合材料包含面心立方Pt-Ru合金纳米晶体和间隙三元金属磷化物相的原始立方纳米晶体（标识为PtRuP_2）的混合物。含有大量纳米PtRuP_2的纳米复合材料的性能与市售Pt / Ru /碳纳米复合材料一样，在直接甲醇燃料电池中具有阳极催化剂的作用。尽管通过消除所有磷源可以最好地实现Pt-Ru纳米复合材料中金属磷化物相的排除，但通过消除所有磷源可以最佳地实现Pt-Ru纳米复合物合成的存在，但在此类纳米复合物中PtRuP_2的存在并非如此毒甲醇电氧化。建议研究纯PtRuE_x（其中E表示主族杂元素）相的合成和电催化反应性。

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《The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical》 |2003年第23期|共8页
作者
William D. King; James D. Corn; Oliver J. Murphy; Deborah L. Boxall; Edward A. Kenik; Krzysztof C. Kwiatkowski; Stuart R. Stock; C. M. Lukehart;
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中图分类物理化学（理论化学）、化学物理学;
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1. Pt-Ru and Pt-Ru-P/Carbon Nanocomposites: Synthesis, Characterization, and Unexpected Performance as Direct Methanol Fuel Cell (DMFC) Anode Catalysts [J] . William D. King, James D. Corn, Oliver J. Murphy, The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2003,第23期

机译：Pt-Ru和Pt-Ru-P /碳纳米复合材料：直接甲醇燃料电池（DMFC）阳极催化剂的合成，表征和意外性能
2. A Pt-Ru/Graphitic Carbon Nanofiber Nanocomposite Exhibiting High Relative Performance as a Direct-Methanol Fuel Cell Anode Catalyst [J] . Eve S. Steigerwalt, Gregg A. Deluga, David E. Cliffel, The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2001,第34期

机译：具有较高相对性能的Pt-Ru /石墨碳纳米纤维纳米复合材料作为直接甲醇燃料电池阳极催化剂
3. Pt-Ru supported on double-walled carbon nanotubes as high-performance anode catalysts for direct methanol fuel cells [J] . Li WZ, Wang X, Chen ZW, The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2006,第31期

机译：Pt-Ru负载在双壁碳纳米管上，作为直接甲醇燃料电池的高性能阳极催化剂
4. NOVEL SOL-GEL SYNTHESIS AND CHARACTERIZATION OF HIGH-SURFACE-AREA Pt-Ru CATALYSTS AS ANODES FOR DIRECT METHANOL FUEL CELLS [C] . Moni Kanchan Datta, Jin Yong Kim, Prashant N. Kumta, Annual Meeting and Exposition of the American Ceramic Society . 2006

机译：新型溶胶 - 凝胶合成与高表面积Pt-Ru催化剂作为直接甲醇燃料电池的阳极
5. Synthesis, activation and electrochemical study of platinum and platinum-based bimetallic nanoparticles for anode catalysts of direct methanol fuel cells (DMFCs). [D] . Liu, Zhufang. 2007

机译：直接甲醇燃料电池（DMFC）阳极催化剂用铂和铂基双金属纳米粒子的合成，活化和电化学研究。
6. Novel Anodic Catalyst Support for Direct Methanol Fuel Cell: Characterizations and Single-Cell Performances [O] . N. Abdullah, S. K. Kamarudin, L. K. Shyuan 2018

机译：直接甲醇燃料电池的新型阳极催化剂支持：表征和单电池性能
7. A solid-polymer-electrolyte direct methanol fuel cell (DMFC) with Pt-Ru nanoparticles supported onto poly(3,4-ethylenedioxythiophene) and polystyrene sulphonic acid polymer composite as anode [O] . K. K. Tintula, S. Pitchumani, P. Sridhar, 2010

机译：用Pt-Ru纳米粒子的固体聚合物 - 电解质直接甲醇燃料电池（DMFC）负载在聚（3,4-亚乙基氧基噻吩）和聚苯乙烯磺酸聚合物复合材料上作为阳极

Pt-Ru and Pt-Ru-P/Carbon Nanocomposites: Synthesis, Characterization, and Unexpected Performance as Direct Methanol Fuel Cell (DMFC) Anode Catalysts

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