Structure and Transport Properties of PEO-Li↓(2)O·3B↓(2)O↓(3) Mixed-Phase Composites

E. Quartarone; P. Mustarelli; C. Tomasi

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Structure and Transport Properties of PEO-Li↓(2)O·3B↓(2)O↓(3) Mixed-Phase Composites

机译：PEO-Li↓（2）O·3B↓（2）O↓（3）混合相复合材料的结构与输运性能

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The conductivity of poly(ethylene oxide) (PEO) based electrolytes can be enhanced by addition of ceramic fillers. We study the properties of composite host matrices obtained by adding to PEO a lithium triborate glass prepared by sol-gel. By means of X-ray diffraction and 13C NMR at the magic angle, we show that there is no chemical interaction among the PEO chains and the filler. Lithium cations enter the PEO structure and increase the polymer amorphous phase by creating transient cross-links. The conductivity data are analyzed in terms of the Meyer-Neldel equation.

机译：聚（环氧乙烷）（PEO）基电解质的电导率可通过添加陶瓷填料来提高。我们研究了通过向PEO中添加溶胶-凝胶法制备的三硼酸锂玻璃获得的复合基质的性能。通过在魔角处的X射线衍射和13C NMR，我们表明PEO链和填料之间没有化学相互作用。锂阳离子进入PEO结构，并通过产生瞬时交联而增加聚合物非晶相。电导率数据根据Meyer-Neldel方程进行分析。

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《The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical》 |1998年第48期|共7页
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E. Quartarone; P. Mustarelli; C. Tomasi;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
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1. Structure and Transport Properties of PEO-Li↓(2)O·3B↓(2)O↓(3) Mixed-Phase Composites [J] . E. Quartarone, P. Mustarelli, C. Tomasi The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 1998,第45a48期

机译：PEO-Li↓（2）O·3B↓（2）O↓（3）混合相复合材料的结构与输运性能
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Structure and Transport Properties of PEO-Li↓(2)O·3B↓(2)O↓(3) Mixed-Phase Composites

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