Self-Assembly of Mesoporous Ruthenium-Boron Amorphous Alloy Catalysts withEnhanced Activity in Maltose Hydrogenation to Maltitol

Qi Meng; Hui Li; Hexing Li

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Self-Assembly of Mesoporous Ruthenium-Boron Amorphous Alloy Catalysts withEnhanced Activity in Maltose Hydrogenation to Maltitol

机译：麦芽糖加氢制麦芽糖醇活性增强的介孔钌-硼非晶态合金催化剂的自组装

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Ru—B amorphous alloy nanospheres with mesoporous structure were synthesized by chemical reduction of Ru(III) ions with BH_4~- ions coassembling with Brij56 surfactant molecules in lyotropic liquid crystalline phase. During liquid-phase maltose hydrogenation, such mesoporous catalyst exhibited much higher activity than the regular Ru—B solid nanoparticles, obviously owing to the higher surface area. Meanwhile, the mesoporous structure in the Ru—B nanospheres could effectively retarded the agglomeration, leading to longer durability. Besides 100% selectivity to maltitol, its activity was nearly 24 times of industrial Raney Ni and could be used repetitively for many times, showing a good potential in practical applications. The formation of mesoporous Ru—B amorphous alloy and the correlation of the catalytic performance to the structural characteristics were discussed based on detailed characterizations.

机译：通过将BH_4〜-离子与Brij56表面活性剂分子共溶在液溶液晶相中还原Ru（III）离子，合成了具有介孔结构的Ru-B非晶态合金纳米球。在液相麦芽糖加氢过程中，这种介孔催化剂比常规的Ru-B固体纳米颗粒具有更高的活性，这显然是由于表面积较大。同时，Ru-B纳米球中的介孔结构可以有效地阻止团聚，从而导致更长的耐久性。除了对麦芽糖醇的100％选择性外，其活性几乎是工业阮内镍的24倍，可以重复使用多次，在实际应用中显示出良好的潜力。在详细表征的基础上，讨论了介孔Ru-B非晶态合金的形成以及催化性能与结构特征的关系。

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《The journal of physical chemistry, C. Nanomaterials and interfaces》 |2008年第30期|共6页
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Qi Meng; Hui Li; Hexing Li;
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中图分类特种结构材料;表面现象的物理化学;
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1. Self-Assembly of Mesoporous Ruthenium-Boron Amorphous Alloy Catalysts withEnhanced Activity in Maltose Hydrogenation to Maltitol [J] . Qi Meng, Hui Li, Hexing Li The journal of physical chemistry, C. Nanomaterials and interfaces . 2008,第30期

机译：麦芽糖加氢制麦芽糖醇活性增强的介孔钌-硼非晶态合金催化剂的自组装
2. Selective maltose hydrogenation to maltitol on a ternary Co–P–B amorphous catalyst and the synergistic effects of alloying B and P [J] . Hui Li, Pingfeng Yang, Dongsheng Chu, Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2007,第1期

机译：三元Co–P–B非晶态催化剂上的选择性麦芽糖加氢制麦芽糖醇以及B和P合金化的协同效应
3. Self-assembly of mesoporous Ni-B amorphous alloy catalysts [J] . Hexing Li, Qingfei Zhao, Ying Wan Journal of Catalysis . 2006,第2期

机译：介孔Ni-B非晶态合金催化剂的自组装
4. Self-Assemblies of Magnetic Nanoparticles (MNPs) and Peroxidase Enzymes:Mesoporous Structures and Nanoscale Magnetic Field Effects (nano-MFEs) for Enhanced Activity BioNanoCatalysts (BNCs) [C] . S.C. Corgie, X. Duan, P. Kahawong, NSTI nanotechnology conference and expo;Nanotech conference expo;NSTI-Nanotech 2012;TechConnect world annual conference expo . 2012

机译：磁性纳米粒子（MNP）和过氧化物酶的自组装：增强活性的生物纳米催化剂（BNC）的介孔结构和纳米级磁场效应（nano-MFEs）。
5. Amorphous Ni-Nb-Y Alloys as Hydrogen Evolution Electrocatalysts [D] . Ghobrial, Samy. 2019

机译：无定形的Ni-NB-Y合金作为氢气进化电催化剂
6. Self-assembly of a mesoporous ZnS/mediating interface/CdS heterostructure with enhanced visible-light hydrogen-production activity and excellent stability [O] . Kui Li, Rong Chen, Shun-Li Li, 2015

机译：自组装介孔ZnS /介导界面/ CdS异质结构具有增强的可见光产氢活性和出色的稳定性
7. Retraction: Honeycomb-like Co–B amorphous alloy catalysts assembled by a solution plasma process show enhanced catalytic hydrolysis activity for hydrogen generation [O] . Dong Ge Tong 2020

机译：收缩：通过溶液等离子体工艺组装的蜂窝状的Co-B非晶合金催化剂，显示出氢产生的增强催化水解活性

Self-Assembly of Mesoporous Ruthenium-Boron Amorphous Alloy Catalysts withEnhanced Activity in Maltose Hydrogenation to Maltitol

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