Sonochemical One-Pot Synthesis of Carbon Nanotube-Supported Rhodium Nanoparticles for Room-Temperature Hydrogenation of Arenes

Horng-Bin Pan; Chien M. Wai

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Sonochemical One-Pot Synthesis of Carbon Nanotube-Supported Rhodium Nanoparticles for Room-Temperature Hydrogenation of Arenes

机译：碳纳米管负载铑纳米粒子的声化学一锅法合成用于芳烃的室温加氢

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Fine rhodium (Rh) nanoparticles with an average diameter of 2.5 ± 0.7 nm can be deposited uniformly on surfaces of carboxylate functionalized multiwalled carbon nanotubes (MWNTs) by a simple one-step sonochemical method in an ethanol solution containing RhCl3 and an organic reducing agent borane morpholine complex (C4H12BNO). The carbon nanotube (CNT)-supported Rh nanoparticles are highly active and reusable catalysts for hydrogenation of benzene and its derivatives at room temperature. Complete ring saturation of polycyclic aromatic hydrocarbons (PAHs) can be achieved under mild hydrogenation conditions using the Rh/MWNT catalyst that can not be done by commercially available Rh nanocatalysts. This one-pot synthesis technique provides a simple and rapid way of making highly active and recyclable CNT-supported nanocatalysts for low-temperature hydrogenation reactions.

机译：通过简单的一步声化学方法，在含有RhCl3和有机还原剂硼烷的乙醇溶液中，平均直径为2.5±0.7 nm的细铑（Rh）纳米颗粒可以均匀地沉积在羧酸盐官能化的多壁碳纳米管（MWNT）的表面上吗啉复合物（C4H12BNO）。碳纳米管（CNT）负载的Rh纳米颗粒是高活性且可重复使用的催化剂，用于在室温下氢化苯及其衍生物。使用Rh / MWNT催化剂可以在温和的氢化条件下实现多环芳烃（PAHs）的完全环饱和，而Rh / MWNT催化剂是商业上无法获得的Rh纳米催化剂无法做到的。这种一锅法合成技术提供了一种简单，快速的方法来制备用于低温加氢反应的高活性且可回收的CNT负载型纳米催化剂。

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《The journal of physical chemistry, C. Nanomaterials and interfaces》 |2009年第46期|共7页
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Horng-Bin Pan; Chien M. Wai;
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中图分类物理化学（理论化学）、化学物理学;
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1. Sonochemical One-Pot Synthesis of Carbon Nanotube-Supported Rhodium Nanoparticles for Room-Temperature Hydrogenation of Arenes [J] . Horng-Bin Pan, Chien M. Wai The journal of physical chemistry, C. Nanomaterials and interfaces . 2009,第46期

机译：碳纳米管负载铑纳米粒子的声化学一锅法合成用于芳烃的室温加氢
2. An electrochemical sensor prepared by sonochemical one-pot synthesis of multi-walled carbon nanotube-supported cobalt nanoparticles for the simultaneous determination of paracetamol and dopamine [J] . Aysegul Kutluay, Mehmet Aslanoglu Analytica chimica acta . 2014,第Null期

机译：通过声化学一锅法合成多壁碳纳米管负载的钴纳米颗粒制备的电化学传感器，用于同时测定扑热息痛和多巴胺
3. Relative Catalytic Activities of Carbon Nanotube-Supported Metallic Nanoparticles for Room-Temperature Hydrogenation of Benzene [J] . Byunghoon Yoon, Horng-Bin Pan, Chien M. Wai The journal of physical chemistry, C. Nanomaterials and interfaces . 2009,第4期

机译：碳纳米管负载的金属纳米粒子对苯室温加氢的相对催化活性
4. One-pot sonochemical synthesis of Fe_(1_x)Gu_xCr_2S_4 chalcospinels [C] . Manju Lata Rao, S. Sundar Manoharan Joint MMM-Intermag Conference . 2007

机译：FE_（1_x）GU_XCR_2S_4 CHALCOSPINELS的单壶SOPOOPEMICAL合成
5. The synthesis of rhodium nanoparticles in conventional and alternative media as catalysts for arene hydrogenation. [D] . Stratton, Samantha. 2012

机译：在常规介质和替代介质中作为芳烃氢化的催化剂合成铑纳米粒子。
6. One-Pot Sonochemical Synthesis of ZnO Nanoparticles for Photocatalytic Applications Modelling and Optimization [O] . Muhammad Tayyab Noman, Michal Petru, Jiří Militký, 2020

机译：一锅超声化学合成ZnO纳米粒子的光催化应用建模和优化
7. Ethanol Synthesis by Catalytic Hydrogenation of Carbon Dioxide over Promoted Rhodium Catalysts. I. The Effect of Additives on Ethanol Synthesis by Catalytic Hydrogenation of Carbon Dioxide over Silica Supported Rhodium Catalysts. [O] . Hitoshi KUSAMA, Kazuhiro SAYAMA, Kiyomi OKABE, 1995

机译：通过促进铑催化剂的二氧化碳催化氢化乙醇合成。 I.二氧化硅上二氧化碳催化氢化添加剂对乙醇合成的作用。

Sonochemical One-Pot Synthesis of Carbon Nanotube-Supported Rhodium Nanoparticles for Room-Temperature Hydrogenation of Arenes

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