Porous Palladium Nanoflowers that Have Enhanced Methanol Electro-Oxidation Activity

Zhen Yin; Huajun Zheng; Ding Ma

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Porous Palladium Nanoflowers that Have Enhanced Methanol Electro-Oxidation Activity

机译：具有增强的甲醇电氧化活性的多孔钯纳米花

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A liquid phase approach was used for the synthesis of novel porous Pd nanoflowers by the self-organization of primary nanoparticle building blocks.Palladium acetylacetonate was used as the metal precursor with 1,2-hexadecanediol as the reduction agent.The porous Pd nanostructure obtained has an average size of 50 nm and was composed of fhree-dimensionally connected Pd nanoparticles with an average diameter of 5.5 nm.The new Pd nanostructure has higher electrocatalytic activity and better stability for the electro-oxidation of methanol in an alkaline media than Pd nanoparticles.

机译：液相法通过初级纳米粒子结构单元的自组织合成新颖的多孔Pd纳米花，以乙酰丙酮钯为金属前体，以1,2-十六烷二醇为还原剂，得到的多孔Pd纳米结构具有这种新型Pd纳米结构的平均尺寸为50 nm，由平均尺寸为5.5 nm的三维连接的Pd纳米颗粒组成。与Pd纳米颗粒相比，这种新型Pd纳米结构在碱性介质中具有更高的电催化活性和对甲醇电氧化的稳定性。

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《The journal of physical chemistry, C. Nanomaterials and interfaces》 |2009年第3期|共5页
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Zhen Yin; Huajun Zheng; Ding Ma;
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正文语种 eng
中图分类特种结构材料;表面现象的物理化学;
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3. Porous Palladium Nanoflowers that Have Enhanced Methanol Electro-Oxidation Activity [J] . Zhen Yin, Huajun Zheng, Ding Ma The journal of physical chemistry, C. Nanomaterials and interfaces . 2009,第3期

机译：具有增强的甲醇电氧化活性的多孔钯纳米花
4. Enhanced catalytic activity of palladium nanoparticles confined inside porous carbon in methanol electro-oxidation [J] . Datta Abheek, Kapri Sutanu, Bhattacharyya Sayan Green chemistry . 2015,第3期

机译：在甲醇电氧化作用下，封闭在多孔碳中的钯纳米颗粒的催化活性增强
5. Simple one-pot synthesis of platinum-palladium nanoflowers with enhanced catalytic activity and methanol-tolerance for oxygen reduction in acid media [J] . Jie-Ning Zheng, Li-Li He, Fang-Yi Chen, Electrochimica Acta . 2014,第Null期

机译：简单的一锅法合成铂-钯纳米花，具有增强的催化活性和耐甲醇性，可在酸性介质中还原氧
6. Electrochemical Study of Palladium-Based Bimetallic Electrocatalysts Supported on Carbon Vulcan XC72R for Methanol Electro-Oxidation in Alkaline Media [C] . V. A. Medina Rojano, E. Chinarro Martin, M. G. Montes de Oca, National Congress of the Mexican Society of Electrochemistry . 2019

机译：碱性介质中碳硫磺XC72R碳氟XC72R碳氟XC72R的电化学研究
7. Exploring the structure-activity relationship of platinum and platinum-based electro-catalysts for the methanol electro-oxidation [D] . Levendorf, Augusta M. 2013

机译：探索铂和铂基电催化剂在甲醇电氧化中的构效关系
8. Preparation of Pt Ag alloy nanoisland/graphene hybrid composites and its high stability and catalytic activity in methanol electro-oxidation [O] . Lili Feng, Guo Gao, Peng Huang, 2011

机译：Pt Ag合金纳米岛/石墨烯杂化复合材料的制备及其在甲醇电氧化中的高稳定性和催化活性
9. Self-Stable WP/C Support with Excellent Cocatalytic Functionality for Pt: Enhanced Catalytic Activity and Durability for Methanol Electro-Oxidation [O] . -1

机译：具有优异的PT含有优异的助催化功能的自稳态WP / C：增强催化活性和甲醇电氧化的耐久性

Porous Palladium Nanoflowers that Have Enhanced Methanol Electro-Oxidation Activity

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