Direct Structural Understanding of a Topochemical Solid State Photopolymerization Reaction

Fang Guo; Javier Marti-Rujas; Zhigang Pan

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Direct Structural Understanding of a Topochemical Solid State Photopolymerization Reaction

机译：对拓扑化学固态光聚合反应的直接结构理解

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Hitherto, direct structural characterization of polycrystalline product phases obtained in solid state polymerization reactions has been limited by the lack of appropriate experimental techniques for structure determination. This paper demonstrates the opportunity to apply modern powder X-ray diffraction techniques for carrying out complete structure determination in such cases, by reporting the structural properties of the polymer phase obtained in the solid state photopolymerization reaction of 2,5-distyrylpyrazine. The structure of the polymer phase, for which structure solution was carried out using the direct-space genetic algorithm technique followed by Rietveld refinement, demonstrates directly the topochemical nature of this solid state reaction.

机译：迄今为止，在固态聚合反应中获得的多晶产物相的直接结构表征受到缺乏合适的用于确定结构的实验技术的限制。本文通过报告在2,5-二苯乙烯基吡嗪固态光聚合反应中获得的聚合物相的结构特性，证明了在这种情况下应用现代粉末X射线衍射技术进行完整结构确定的机会。聚合物相的结构（使用直接空间遗传算法技术进行结构求解，然后进行Rietveld精炼）直接证明了该固态反应的拓扑化学性质。

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《The journal of physical chemistry, C. Nanomaterials and interfaces》 |2008年第50期|共4页
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Fang Guo; Javier Marti-Rujas; Zhigang Pan;
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正文语种 eng
中图分类特种结构材料;表面现象的物理化学;
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1. Direct Structural Understanding of a Topochemical Solid State Photopolymerization Reaction [J] . Fang Guo, Javier Marti-Rujas, Zhigang Pan The journal of physical chemistry, C. Nanomaterials and interfaces . 2008,第50期

机译：对拓扑化学固态光聚合反应的直接结构理解
2. Regiospecific topochemical reactions controlled by trifluoromethyl directing groups [J] . Liu J, Boarman KJ Chemical Communications . 2005,第3期

机译：三氟甲基指导基团控制的区域特异性拓扑化学反应
3. Two-Dimensional Solid-State Topochemical Reactions of 10,12- Pentacosadiyn-1-ol Adsorbed on Graphite [J] . Daisuke Takajo, Akira Inaba, Koichi Sudoh Langmuir: The ACS Journal of Surfaces and Colloids . 2014,第10期

机译：石墨上吸附的10,12-五元乙二炔-1-醇的二维固态拓扑化学反应
4. TOPOCHEMICAL SOLID-PHASE REACTIONS OF FLUORINATIONAND THE PROBLEMS OF SELECTIVE FUNCTIONALIZATIONOF FULLERENES WITH SMALL INORGANIC GROUPS [C] . A . Ya., Borschev ski i N, S. Chilingarov, International Symposium on Fullerenes, Nanotubes, and Carbon Nanoclusters . 2003

机译：氟化的Topochemical固相反应和小无机组富勒烯选择性官能化问题
5. The topochemical [2+2] photocycloaddition reaction of alpha-trans-cinnamic acid: A perspective from solid-state NMR measurements. [D] . Nieuwendaal, Ryan Christian. 2008

机译：α-反式肉桂酸的拓扑化学[2 + 2]光环加成反应：固态NMR测量的透视图。
6. Crystal chemistry and photomechanical behavior of 34-dimethoxycinnamic acid: correlation between maximum yield in the solid-state topochemical reaction and cooperative molecular motion [O] . Manish Kumar Mishra, Arijit Mukherjee, Upadrasta Ramamurty, 2015

机译：34-二甲氧基肉桂酸的晶体化学和光机械行为：固态拓扑化学反应中最大产率与分子运动的相关性
7. Crystal chemistry and photomechanical behavior of 3,4-dimethoxycinnamic acid: correlation between maximum yield in the solid-state topochemical reaction and cooperative molecular motion [O] . Mishra, Manish Kumar, Mukherjee, Arijit, Ramamurty, Upadrasta, 2015

机译：3,4-二甲氧基肉桂酸的晶体化学和光机械行为：固态拓扑化学反应中最大产率与分子运动的相关性
8. Microstructural Aspects of Gas-Solid Reactions [R] . Rau, M. F. 1985

机译：气固反应的微观结构方面

Direct Structural Understanding of a Topochemical Solid State Photopolymerization Reaction

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