Fischer-tropsch mechanism revisited: Alternative pathways for the production of higher hydrocarbons from synthesis gas

Inderwildi OR; Jenkins SJ; King DA

首页> 外文期刊>The journal of physical chemistry, C. Nanomaterials and interfaces >Fischer-tropsch mechanism revisited: Alternative pathways for the production of higher hydrocarbons from synthesis gas

【24h】

Fischer-tropsch mechanism revisited: Alternative pathways for the production of higher hydrocarbons from synthesis gas

机译：费歇尔-托普施奇机理再探：从合成气生产高级烃的替代途径

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Evidence from density functional theory calculations that the main reaction pathway for the Fischer-Tropsch process on Co{0001} is not the carbide mechanism but an alternative branch starting with the hydrogenation of CO to an oxymethylidyne species. We show that hydrogenation is the main reaction path at realistic pressure using microkinetic simulations and thereby bridge the pressure gap in heterogeneous catalysis.

机译：从密度泛函理论计算得出的证据表明，Co {0001}上的Fischer-Tropsch过程的主要反应途径不是碳化物机理，而是从CO加氢成羟甲基亚炔类开始的替代分支。我们显示氢化是在实际压力下使用微动力学模拟的主要反应路径，从而弥合了多相催化中的压力差。

著录项

来源
《The journal of physical chemistry, C. Nanomaterials and interfaces》 |2008年第5期|共3页
作者
Inderwildi OR; Jenkins SJ; King DA;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类特种结构材料;表面现象的物理化学;
关键词
CO(0001) SURFACES; CO DISSOCIATION; OXIDATION; HYDROGENATION; CATALYSTS; DECOMPOSITION; ADSORPTION; DESORPTION; PRESSURE; SCIENCE;

机译：CO（0001）表面;CO离解;氧化;加氢;催化剂;分解;吸附;脱附;压力;科学;

相似文献

外文文献
中文文献
专利

1. Fischer-tropsch mechanism revisited: Alternative pathways for the production of higher hydrocarbons from synthesis gas [J] . Inderwildi OR, Jenkins SJ, King DA The journal of physical chemistry, C. Nanomaterials and interfaces . 2008,第5期

机译：费歇尔-托普施奇机理再探：从合成气生产高级烃的替代途径
2. An Na-modified Fe@C core-shell catalyst for the enhanced production of gasoline-range hydrocarbons via Fischer-Tropsch synthesis [J] . Ma Guangyuan, Xu Yanfei, Wang Jie, RSC Advances . 2020,第18期

机译：一种Na-改性的Fe @ C核壳催化剂，用于通过Fischer-Tropsch合成增强汽油烃的生产
3. Fischer-Tropsch synthesis on Co-Al2O3-(promoter)/ZSM5 hybrid catalysts for the production of gasoline range hydrocarbons [J] . Ryu Jae-Hong, Kang Suk-Hwan, Kim Jin-Ho, The Korean journal of chemical engineering . 2015,第10期

机译：Co-Al2O3-（助催化剂）/ ZSM5杂化催化剂的费托合成用于生产汽油范围的烃
4. Generation of Light Hydrocarbons through Fischer-Tropsch Synthesis: Identification of Potentially Dominant Catalytic Pathways via the Graph-theoretic Method and Energetic Analysis [C] . Yu-Chuan Lin, L.T. Fan, Shahram Shafie American Institute of Chemical Engineers Annual Meeting . 2007

机译：通过Fischer-Tropsch合成产生轻质烃：通过图解方法和能量分析鉴定潜在的主要催化途径
5. Supercritical phase Fischer-Tropsch synthesis inhibition of carbon dioxide selectivity for enhanced hydrocarbon production. [D] . Benoit, Jeremiah. 2008

机译：费托合成的超临界相抑制了二氧化碳选择性，从而提高了烃的产量。
6. Sugar analog synthesis by in vitro biocatalytic cascade: A comparison of alternative enzyme complements for dihydroxyacetone phosphate production as a precursor to rare chiral sugar synthesis [O] . Carol J. Hartley, Nigel G. French, Judith A. Scoble, 2011

机译：通过体外生物催化级联法合成糖类似物：比较生产磷酸二羟基丙酮作为罕见手性糖合成前体的替代酶补体
7. Physico-Chemical Investigations on Catalytic Mechanism. II. Note on The Fischer-Tropsch Synthesis of Hydrocarbons with Special Reference to its Reaction Mechanism [O] . Senzo Hamai 1941

机译：催化机制的物理化学研究。 II。关于碳氢化合物的烃基合成烃的注意事项及其反应机制

Fischer-tropsch mechanism revisited: Alternative pathways for the production of higher hydrocarbons from synthesis gas

摘要

著录项

相似文献

相关主题

期刊订阅