Hexagonally packed Pd nanoarray catalyst for liquid-phase enantioselective hydrogenation of acetophenone to R-(+)-1-phenylethanol in the presence of S-proline

Chen XY; Lou ZY; Qiao MH; Fan KN; Tsang SC; He HY

首页> 外文期刊>The journal of physical chemistry, C. Nanomaterials and interfaces >Hexagonally packed Pd nanoarray catalyst for liquid-phase enantioselective hydrogenation of acetophenone to R-(+)-1-phenylethanol in the presence of S-proline

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Hexagonally packed Pd nanoarray catalyst for liquid-phase enantioselective hydrogenation of acetophenone to R-(+)-1-phenylethanol in the presence of S-proline

机译：在S-脯氨酸存在下，六方堆积的Pd纳米阵列催化剂用于苯乙酮的液相对映异构氢化为R-（+）-1-苯基乙醇

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Hexagonally packed Pd nanoarray catalyst was prepared via the "two solvents" strategy with mesoporous molecular sieve SBA-15 as a hard template. By using S-proline as the chiral modifier, the catalyst exhibited superior activity and selectivity in liquid-phase hydrogenation of acetophenone to R-(+)-1-phenylethanol with up to 100% chemoselectivity and 28.8% enantiomeric excess. The presence of S-proline and the regular hexagonal mesostructure of the Pd nanoarray catalyst are crucial for its superior catalytic performance.

机译：通过“两种溶剂”策略以中孔分子筛SBA-15作为硬模板制备了六方堆积的Pd纳米阵列催化剂。通过使用S-脯氨酸作为手性改性剂，该催化剂在苯乙酮向R-（+）-1-苯基乙醇的液相加氢中表现出优异的活性和选择性，化学选择性高达100％，对映体过量达28.8％。 Pd纳米阵列催化剂中S-脯氨酸的存在和规则的六边形介观结构对其优越的催化性能至关重要。

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《The journal of physical chemistry, C. Nanomaterials and interfaces》 |2008年第5期|共5页
作者
Chen XY; Lou ZY; Qiao MH; Fan KN; Tsang SC; He HY;
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正文语种 eng
中图分类特种结构材料;表面现象的物理化学;
关键词
MESOPOROUS SILICA; SBA-15;

机译：介孔二氧化硅;SBA-15;

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1. Hexagonally packed Pd nanoarray catalyst for liquid-phase enantioselective hydrogenation of acetophenone to R-(+)-1-phenylethanol in the presence of S-proline [J] . Chen XY, Lou ZY, Qiao MH, The journal of physical chemistry, C. Nanomaterials and interfaces . 2008,第5期

机译：在S-脯氨酸存在下，六方堆积的Pd纳米阵列催化剂用于苯乙酮的液相对映异构氢化为R-（+）-1-苯基乙醇
2. Preparation of 1-phenylethanol by selective hydrogenation of acetophenone over alumina-supported Co catalysts [J] . Xin Bo Zhang Reaction Kinetics, Mechanisms and Catalysis . 2011,第2期

机译：氧化铝负载的钴催化剂上苯乙酮的选择性加氢制备1-苯基乙醇
3. Preparation of 1-phenylethanol by selective hydrogenation of acetophenone oyer alumina-supported Co catalysts [J] . Xin Bo Zhang Reaction kinetics,mechanisms and catalysis . 2011,第2期

机译：通过苯乙酮或氧化铝负载的钴催化剂的选择性加氢制备1-苯基乙醇
4. A Comparative Study of Pd/SiO_2 And Pd/MCM-41 Catalysts in Liquid-Phase Hydrogenation [C] . Kanda Pattamakomsan, Joongjai Panpranot, Piyasan Praserthdam Asia-Pacific Congress on Catalysis . 2003

机译：Pd / SiO_2和Pd / MCM-41催化剂在液相氢化中的比较研究
5. Investigation of Pd-Ceria Catalysts for Selective Hydrogenation of Acetylene in Ethylene [D] . Xie, Wentao 2017

机译：用于乙烯中乙炔选择性加氢的Pd-Ceria催化剂的研究
6. Phosphorus as a promoter of a nickel catalyst to obtain 1-phenylethanol from chemoselective hydrogenation of acetophenone [O] . Dolly Carolina Costa, Analía Leticia Soldati, José Fernando Bengoa, 2019

机译：磷作为镍催化剂的促进剂通过苯乙酮的化学选择性加氢反应获得1-苯基乙醇
7. One-pot synthesis of ethylbenzene/1-phenylethanol and γ-butyrolactone from simultaneous acetophenone hydrogenation and 1,4-butanediol dehydrogenation over copper based catalysts: effects of the support [O] . Hari Prasad Reddy Kannapu, Young-Woong Suh, Anand Narani, 2017

机译：单罐合成乙苯/ 1-苯基乙醇和γ-丁内酯的同时乙酮氢化和基于铜基催化剂的1,4-丁二醇脱氢：载体的影响
8. The Strengthening of Hexagonal Close-Packed Materials Due to the Presence of Grain Boundaries. [R] . prasad, y. v. r. k. madhava, n. m. 1975

机译：由于晶界的存在，六角密堆材料的强化。

Hexagonally packed Pd nanoarray catalyst for liquid-phase enantioselective hydrogenation of acetophenone to R-(+)-1-phenylethanol in the presence of S-proline

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