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Active Thermochemical Tables: dissociation energies of several homonuclear first-row diatomics and related thermochemical values

机译:活性热化学表:几种同核第一行双原子的解离能及相关的热化学值

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摘要

The current Active Thermochemical Tables (ATcT) results for the bond dissociation energies of the homonuclear diatomics H2, C2, N2, O2, and F2 are reported and discussed. The role and origin of the distributed provenance of ATcT values is analyzed. Ramifications in terms of the enthalpies of formation of H, C, N, O, and F atoms, which are fundamental thermochemical quantities, are presented. In addition, the current ATcT bond dissociation energies and enthalpies of formation of HF, CH, CO, CN, NO, OH, CO2, H20, and triplet and singlet CH2 are also reported.
机译:报告并讨论了当前活性热化学表(ATcT)的同核双原子H2,C2,N2,O2和F2的键解离能的结果。分析了ATcT值的分布式来源的作用和来源。提出了以H,C,N,O和F原子的形成焓为基础的支化作用,它们是基本的热化学量。另外,还报道了当前的ATcT键解离能和形成HF,CH,CO,CN,NO,OH,CO 2,H 2 O以及三重态和单重态CH 2的焓。

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