Electronic structure of hybrid interfaces of poly(9,9-dioctylfluorene)

Greczynski G.; Salaneck WR.; Fahlman M.

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Electronic structure of hybrid interfaces of poly(9,9-dioctylfluorene)

机译：聚（9,9-二辛基芴）杂化界面的电子结构

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In this Letter we report the results of a study of the energy level alignment at interfaces between ultra-thin films of poly(9,9-dioctylfluorene) and AlxOy SiO2 or gold substrates, prepared under ambient (air) conditions. In all the cases, vacuum level alignment occurs, and the work function tracks that of the substrates. There is no evidence of band bending in the pristine polymer layers up to 1100 Angstrom in film thickness. Upon increasing the electrical conductivity of the polymer films by continuous doping with sodium under ultra-high-vacuum conditions, the energy levels of the polymer film gradually shift towards higher binding energies and finally become substrate independent. (C) 2000 Elsevier Science B.V. All rights reserved. [References: 21]

机译：在这封信中，我们报告了在环境（空气）条件下制备的聚（9,9-二辛基芴）超薄膜与AlxOy SiO2或金基底之间的界面处能级对准的研究结果。在所有情况下，都会发生真空水平对准，并且功函数会跟踪基板的真空水平。没有证据表明原始聚合物层的膜厚度高达1100埃时带弯曲。通过在超高真空条件下连续掺杂钠来增加聚合物膜的电导率后，聚合物膜的能级逐渐向更高的结合能转移，并最终变得与基底无关。（C）2000 Elsevier Science B.V.保留所有权利。 [参考：21]

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《Chemical Physics Letters》 |2000年第6期|共6页
作者
Greczynski G.; Salaneck WR.; Fahlman M.;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
Photoemission spectroscopy; Surface photovoltage; Level alignment; Energy; Polymer; Molecules; Devices; Films; Metal;

机译：光电子能谱;表面光电压;能级对准;能量;聚合物;分子;器件;薄膜;金属;

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1. Electronic structure of hybrid interfaces of poly(9,9-dioctylfluorene) [J] . Greczynski G., Salaneck WR., Fahlman M. Chemical Physics Letters . 2000,第5a6期

机译：聚（9,9-二辛基芴）杂化界面的电子结构
2. Interfacial structure in conjugated polymers: Characterization and control of the interface between poly(9,9-dioctylfluorene) and poly(9,9-dioctylfluorene-alt-benzothiadiazole) [J] . Higgins AM, Martin SJ, Geoghegan M, Macromolecules . 2006,第19期

机译：共轭聚合物的界面结构：表征和控制聚（9,9-二辛基芴）和聚（9,9-二辛基芴-alt-苯并噻二唑）之间的界面
3. Hybrid interfaces of poly(9,9-dioctylfluorene) employing thin insulating layers of CsF: A photoelectron spectroscopy study [J] . G.Greczynski, M.Fahlman, W.R.Salaneck The Journal of Chemical Physics . 2001,第19期

机译：使用CsF绝缘薄层的聚（9,9-二辛基芴）的杂化界面：光电子能谱研究
4. Interface formation between poly (9,9-dioctylfluorene) and alkali metals investigated by photoemission spectroscopy [C] . M.K. Fung, S.L. Lai, S.N. Bao, International workshop on inorganic and organic electroluminescence . 2002

机译：聚（9,9-二辛基氟烯）与光学激光谱研究的碱金属之间的界面形成
5. Improving the Spectral Stability of Poly(9,9-dioctylfluorene) (PFO) Through the use of Aromatic Ethers. [D] . Sirtonski, Matthew Ron. 2011

机译：通过使用芳族醚提高聚（9,9-二辛基芴）（PFO）的光谱稳定性。
6. Spectroscopic properties of poly(99‐dioctylfluorene) thin films possessing varied fractions of β‐phase chain segments: enhanced photoluminescence efficiency via conformation structuring [O] . Aleksandr Perevedentsev, Nathan Chander, Ji‐Seon Kim, -1

机译：具有不同比例的β相链段的聚（99-二辛基芴）薄膜的光谱性质：通过构象结构提高了光致发光效率
7. Fabrication and Microelectronic Properties of Hybrid Organic–Inorganic (poly(9,9, dioctylfluorene)/p-Si) Heterojunction for Electronic Applications [O] . Muhammad Tahir, Muhammad Ilyas, Fakhra Aziz, 2020

机译：电子应用杂种有机无机的制造和微电子性能（聚（9,9，二辛基氟烯）/ P-Si）异质结
8. Study of the Interface Electronic Structure of a Model Metal-Semiconductor Interface [R] . Lowy, D. N., Madhukar, A. 1978

机译：金属 - 半导体模型接口电子结构的研究

Electronic structure of hybrid interfaces of poly(9,9-dioctylfluorene)

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