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首页> 外文期刊>Theoretical and Experimental Chemistry >PHYSICAL AND CHEMICAL PROBLEMS OF THE CREATION OF PHOTOSTABLE CONVERTERS OF LIGHT ENERGY ON THE BASIS OF DYED POLYMERS
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PHYSICAL AND CHEMICAL PROBLEMS OF THE CREATION OF PHOTOSTABLE CONVERTERS OF LIGHT ENERGY ON THE BASIS OF DYED POLYMERS

机译:基于染色聚合物的光能光稳定转化子的建立的物理和化学问题

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摘要

The main factors affecting the degradation of dyed polymeric matrices by the action of light (conversion of light energy into thermal energy,electron phototransfer,population of triplets,aggregation of dyes,oxidation-reduction processes,interaction with oxygen,including singlet) are analyzed and classified. Their dependence on the structure of the dyes,the nature of the polymer,and the method of dyeing of the latter is examined. Criteria for the creation of lightfast dyed matrices are formulated. Special attention is directed to contemporary light-sensitive materials in which the dye is covalently bonded to the polymer and to organic-inorganic compositions based on them.
机译:分析和影响了光作用下染料聚合物基体降解的主要因素(光能转化为热能,电子光转移,三重态的聚集,染料的聚集,氧化还原过程,与氧的相互作用,包括单重态)。分类。研究了它们对染料结构,聚合物性质以及后者染色方法的依赖性。制定了创建耐光染色基质的标准。特别注意的是当代的光敏材料,其中染料与聚合物共价键合,并与基于它们的有机无机组合物结合。

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