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首页> 外文期刊>Theoretical and Experimental Chemistry >ADSORPTION PROPERTIES OF POROUS MATERIALS BASED ON MACROCYCLIC NICKEL(II) COMPLEXES AND BENZENETRICARBOXYLATE RELATIVE TO WATER, METHANOL, AND HEXANE VAPOR
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ADSORPTION PROPERTIES OF POROUS MATERIALS BASED ON MACROCYCLIC NICKEL(II) COMPLEXES AND BENZENETRICARBOXYLATE RELATIVE TO WATER, METHANOL, AND HEXANE VAPOR

机译:基于大环镍(II)配合物和苯甲酸苄酯的多孔材料对水,甲醇和己烷的吸附性能

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摘要

We have shown that varying the substituents in the cationic component of porous crystal compounds formed by azamacrocyclic nickel(II) complexes and the 1,3,5-benzenetricarboxylate anion has a substantial effect on their adsorption behavior relative to water, methane, and n-hexane vapor. The studied compounds are characterized by reversibility of the changes in the crystal lattices during adsorption/desorption, stoichiometry of the reaction with water vapor with relatively low and hydrolytic stability at high humidity.
机译:我们已经表明,改变由氮杂大环镍(II)配合物和1,3,5-苯三羧酸根阴离子形成的多孔晶体化合物的阳离子成分中的取代基对其吸附行为的影响相对于水,甲烷和n-己烷蒸气。所研究的化合物的特征在于吸附/解吸过程中晶格变化的可逆性,与水蒸气反应的化学计量比(相对较低)以及在高湿度下的水解稳定性。

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