THERMODYNAMIC APPROACH TO PREDICTION OF THE EFFECT OF SIZE ON NANOSTRUCTURE PROPERTIES

K. I. Patrylak; L. K. Patrylak; S. V. Konovalov

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THERMODYNAMIC APPROACH TO PREDICTION OF THE EFFECT OF SIZE ON NANOSTRUCTURE PROPERTIES

机译：预测尺寸对纳米结构性能影响的热力学方法

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Approaches to the prediction of the properties of small particles with diameter down to 1-2 nm are proposed using the Thomson-Kelvin, Clapeyron-Clausius, and Laplace laws as well as the Poynting effect. Particles with minimal dimensions but with a well-formed surface characterized by surface tension were found to be optimal relative to chemical potential.

机译：提出了使用Thomson-Kelvin，Clapeyron-Clausius和Laplace定律以及Poynting效应预测直径小至1-2 nm的小颗粒性质的方法。发现具有最小尺寸但具有以表面张力为特征的结构良好的表面的颗粒相对于化学势是最佳的。

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《Theoretical and Experimental Chemistry》 |2013年第1期|共5页
作者
K. I. Patrylak; L. K. Patrylak; S. V. Konovalov;
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正文语种 eng
中图分类化学;
关键词
small particles; nanostructures; clusters; dimensional effect; thermodynamics; fundamental properties; catalytic activity.;

机译：小颗粒;纳米结构;团簇;尺寸效应;热力学;基本性质;催化活性;

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1. THERMODYNAMIC APPROACH TO PREDICTION OF THE EFFECT OF SIZE ON NANOSTRUCTURE PROPERTIES [J] . K. I. Patrylak, L. K. Patrylak, S. V. Konovalov Theoretical and Experimental Chemistry . 2013,第1期

机译：预测尺寸对纳米结构性能影响的热力学方法
2. Highly Supersaturated Solutions of Amorphous Drugs Approaching Predictions from Configurational Thermodynamic Properties [J] . Matteucci ME, Miller MA, Williams RO, The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2008,第51期

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5. Detailed analysis and critical evaluation of the effects of the pure component parameterization methodology on mixture property predictions for thermodynamic equations of state. [D] . Swaminathan, Saravanan. 2007

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THERMODYNAMIC APPROACH TO PREDICTION OF THE EFFECT OF SIZE ON NANOSTRUCTURE PROPERTIES

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