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THERMOCHEMICAL DATA OF BORON SUBPHOSPHIDE

机译:亚磷酸硼的热化学数据

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Thermochemical data of boron subphosphide are derived from reported decomposition data of cubic boron monophosphide BP. Both reported boron subphosphides, i.e. B6P and B13P2, are taken into account, without claiming either of these to have the reported stoichiometry. The standard heat of formation Delta(f)H(0), the standard entropy S-0, and the heat capacity as a function of temperature C-P,T(0), pf B6P and B13P2 are Delta(f)H(0) = 69.2 -/+ 11.4 kJ/mol, S-0 = 213 -/+ 15 J/mol K, and C-P,T(0) = (42.0 -/+ 0.9) + (0.166 -/+ 0.004) x TJ/mol K, and Delta(f)H(0) = 175 -/+ 4 kJ/mol, S-0 = 462 -/+ 10 J/mol K, and C-P,T(0), = (87.6 -/+ 1.8) + (0.359 -/+ 0.008) x TJ/mol K, respectively. (C) 1997 Elsevier Science B.V. [References: 23]
机译:亚磷化硼的热化学数据来自报道的立方单磷化硼BP的分解数据。两种报告的亚硼化硼,即B6P和B13P2,都被考虑在内,而没有声称其中任何一种具有报告的化学计量。地层标准热量Delta(f)H(0),标准熵S-0和作为温度CP,T(0),pf B6P和B13P2的函数的热容为Delta(f)H(0) = 69.2-/ + 11.4 kJ / mol,S-0 = 213-/ + 15 J / mol K,CP,T(0)=(42.0-/ + 0.9)+(0.166-/ + 0.004)x TJ / mol K,Delta(f)H(0)= 175-/ + 4 kJ / mol,S-0 = 462-/ + 10 J / mol K,CP,T(0),=(87.6-/ + 1.8)+(0.359-/ + 0.008)x TJ / molK。 (C)1997 Elsevier Science B.V. [参考:23]

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