首页> 外文期刊>Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems >Thermodynamics of mixtures containing ethers. PART II - Isothermal x-y data for the ternary system MTBE plus methanol+1-butanol and for two constituent binaries: DISQUAC predictions on VLE of ternary mixtures containing tertiary-alkyl ethers and orga
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Thermodynamics of mixtures containing ethers. PART II - Isothermal x-y data for the ternary system MTBE plus methanol+1-butanol and for two constituent binaries: DISQUAC predictions on VLE of ternary mixtures containing tertiary-alkyl ethers and orga

机译:含醚混合物的热力学。第二部分-三元系统MTBE加甲醇+ 1-丁醇和两个组成的二元体系的等温x-y数据:含叔烷基醚和有机化合物的三元混合物的VLE的DISQUAC预测

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VLE data at 298.15 K (x-y measurements, where x and y are the mole fractions in liquid and vapor phase, respectively) for methanol or 1-butanol + methyl tert-butyl ether (MTBE) and for MTBE + methanol + 1-butanol systems are reported. These data and those available on literature on VLE at isothermal conditions for ternary systems containing tertiary-alkyl ethers (MTBE. tert-amyl methyl ether (TAME)) and organic solvents (hydrocarbons and 1-alkanols) are analyzed in terms of DISQUAC. The model correctly predicts VLE of this type of mixtures using binary parameters only, i.e. neglecting ternary interactions. Results are independent of the mixture considered. (C) 2001 Elsevier Science B.V. All rights reserved. [References: 52]
机译:甲醇或1-丁醇+甲基叔丁基醚(MTBE)和MTBE +甲醇+ 1-丁醇系统在298.15 K时的VLE数据(xy测量,其中x和y分别为液相和气相的摩尔分数)被报道。这些数据和有关等温条件下VLE文献中包含叔烷基醚(MTBE。叔戊基甲基醚(TAME))和有机溶剂(烃和1-烷醇)的三元体系中可获得的数据均按照DISQUAC进行了分析。该模型仅使用二进制参数即可正确预测此类混合物的VLE,即忽略三元相互作用。结果与所考虑的混合物无关。 (C)2001 Elsevier Science B.V.保留所有权利。 [参考:52]

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