Electrodeposition and properties of Zn, Zn-Ni, Zn-Fe and Zn-Fe-Ni alloys from acidic chloride-sulphate electrolytes

I. H. Karahan; H. S. Guder

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Electrodeposition and properties of Zn, Zn-Ni, Zn-Fe and Zn-Fe-Ni alloys from acidic chloride-sulphate electrolytes

机译：酸性氯化物-硫酸盐电解质对Zn，Zn-Ni，Zn-Fe和Zn-Fe-Ni合金的电沉积和性能

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Zn, Zn-Ni, Zn-Fe and Zn-Fe-Ni films have been deposited by electrochemical deposition technique onto steel plate substrates. The objective of this study was to characterise the corrosion properties of these alloys in saline solution for the application as new environmentally friendly sacrificial coatings in the protection of steel structures. The morphological and structural properties of the alloys were systematically studied using XRD and SEM techniques. Cyclic voltammetry of the individual metals was performed to help understand the electroplating process of the films. Grain sizes of the films were calculated using Scherrer's formula. Partial substitution of Zn to Fe and Ni leads to an improvement in the corrosion resistance. Compared with other zinc alloys, the Zn-Ni alloy deposit was the noblest.

机译：Zn，Zn-Ni，Zn-Fe和Zn-Fe-Ni膜已通过电化学沉积技术沉积在钢板基板上。这项研究的目的是表征这些合金在盐溶液中的腐蚀性能，以用作保护钢结构的新型环保牺牲涂层。使用XRD和SEM技术系统地研究了合金的形貌和结构性能。进行了各种金属的循环伏安法，以帮助了解薄膜的电镀过程。使用Scherrer公式计算膜的粒度。将Zn部分替换为Fe和Ni可提高耐蚀性。与其他锌合金相比，Zn-Ni合金沉积物是最高的。

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《Transactions of the Institute of Metal Finishing: The International Journal for Surface Engineering and Coatings》 |2009年第3期|共4页
作者
I. H. Karahan; H. S. Guder;
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原文格式 PDF
正文语种 eng
中图分类冶金工业;
关键词
Zinc-iron group alloys; Thin films; Corrosion; Electrodeposition; XRD;

机译：锌铁基合金;薄膜;腐蚀;电沉积;XRD;

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1. Electrodeposition and properties of Zn, Zn-Ni, Zn-Fe and Zn-Fe-Ni alloys from acidic chloride-sulphate electrolytes [J] . I. H. Karahan, H. S. Guder Transactions of the Institute of Metal Finishing: The International Journal for Surface Engineering and Coatings . 2009,第3期

机译：酸性氯化物-硫酸盐电解质对Zn，Zn-Ni，Zn-Fe和Zn-Fe-Ni合金的电沉积和性能
2. Zn-Ni and Zn-Fe alloy deposits modified by P incorporation: anticorrosion properties [J] . A. R. Ordine, S. L. Diaz, I. C. P. Margarit, Electrochimica Acta . 2004,第17a18期

机译：P结合改性的Zn-Ni和Zn-Fe合金镀层：耐腐蚀性能
3. The Influence of Zinc Concentrarion, pH and Flow Velocity on the Electrodeposition of Zn-Fe alloy Under the High Electrolyte Flow [J] . Satoru Ando, Masaru Sagiyama 表面技術 . 2001,第10期

机译：锌离子浓度，pH值和流速对高电解液流量下锌铁合金电沉积的影响
4. STUDY OF Zn-Fe AND Zn-Fe-Co ALLOYS COATINGS OBTAINED BY ELECTRODEPOSITION FROM ACID BATHS CONTAINING CITRATE IONS [C] . Roberto Zenhei Nakazato, Flavia Cristina Zenith Ferreira, Conceigao Aparecida Matsumoto Dutra ABM International Congress . 2012

机译：通过含柠檬酸盐离子的酸浴电沉积获得的Zn-Fe和Zn-Fe-Co合金涂层的研究
5. Electrodeposition of Ni-W, Ag-W and Ag-Ni-W alloys from thiourea citrate electrolytes [D] . Kola, Avinash Raj. 2016

机译：来自硫酸柠檬酸盐电解质的Ni-W，Ag-W和Ag-Ni-W合金的电沉积
6. Effects of pH Value of the Electrolyte and Glycine Additive on Formation and Properties of Electrodeposited Zn-Fe Coatings [O] . İsmail Hakki Karahan 2013

机译：电解质和甘氨酸添加剂的pH值的影响电沉积锌铁涂层的形成与性能研究
7. The Influence of Zinc Concentrarion, pH and Flow Velocity on the Electrodeposition of Zn-Fe alloy Under the High Electrolyte Flow. [O] . Satoru ANDO, Masaru SAGIYAMA 2001

机译：锌浓度，pH和流速对高电解质流动Zn-Fe合金电沉积的影响。

Electrodeposition and properties of Zn, Zn-Ni, Zn-Fe and Zn-Fe-Ni alloys from acidic chloride-sulphate electrolytes

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