Rheological study of interactions between non-ionic surfactants and polysaccharide thickeners used in textile printing

Rebeka Fijan; Sonja Sostar-Turk; Romano Lapasin

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Rheological study of interactions between non-ionic surfactants and polysaccharide thickeners used in textile printing

机译：纺织品印花中非离子表面活性剂与多糖增稠剂相互作用的流变学研究

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The influence of four non-ionic surfactants(isododecyl and cetyl polyoxyethylene ethers)on aqueous polysaccharide solutions(sodium alginate,guar gum,and sodium carboxymethyl guar),applicable for textile printing pastes,were studied via rheological measurements.Rheology of polysaccharide-surfactant solutions in aqueous matrices is primarily governed by polymer content,which imparts marked shear-thinning and viscoelastic character to the system.Such properties are modulated in moderate but sensible way by changes in surfactant concentration or type.Above 3% surfactants addition to non-substituted guar gum solutions results in a significant impact leading to phase separation and a particular strongly associated phase is formed due to hydrogen bonds between ethylene oxy units from the surfactant and primary hydroxyl groups in guar.A satisfactory fitting of viscosity data is obtained with both the Cross equation and the Roberts-Barnes-Carew model.The experimental results of mechanical spectra can be described quite satisfactory with both the Friedrich-Braun and the generalized Maxwell models.

机译：通过流变测量研究了四种非离子表面活性剂（异十二烷基和鲸蜡基聚氧乙烯醚）对适用于纺织品印花浆料的多糖水溶液（海藻酸钠，瓜尔豆胶和羧甲基瓜尔胶钠）的影响。多糖表面活性剂溶液的流变性水性基体中的聚合物主要受聚合物含量的控制，这会给体系带来显着的剪切稀化和粘弹性特征。通过改变表面活性剂的浓度或类型，这些性能会以适度但明智的方式得到调节.3％以上的表面活性剂以及非取代的瓜尔胶胶溶液会产生重大影响，导致相分离，并且由于瓜尔胶中来自表面活性剂的乙烯氧基单元与伯羟基之间形成氢键，形成了特别牢固的缔合相。和Roberts-Barnes-Carew模型。机械点的实验结果用Friedrich-Braun模型和广义Maxwell模型都可以很好地描述ra。

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《Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides》 |2007年第4期|共10页
作者
Rebeka Fijan; Sonja Sostar-Turk; Romano Lapasin;
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正文语种 eng
中图分类天然化合物;
关键词
Polysaccharide; Textile printing; Non-ionic surfactant; Polymer-surfactant interactions; Viscoelasticity;

机译：多糖;纺织印花;非离子表面活性剂;聚合物-表面活性剂相互作用;粘弹性;

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1. Rheological study of interactions between non-ionic surfactants and polysaccharide thickeners used in textile printing [J] . Rebeka Fijan, Sonja Sostar-Turk, Romano Lapasin Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides . 2007,第4期

机译：纺织品印花中非离子表面活性剂与多糖增稠剂相互作用的流变学研究
2. Interactions between polysaccharide polymer thickener and bifunctional bireactive dye in the presence of nonionic surfactants. Part 1: surface tension and rheological behavior of different polysaccharide solutions [J] . Vanja Kokol Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides . 2002,第3期

机译：在非离子表面活性剂存在下，多糖聚合物增稠剂与双功能双反应性染料之间的相互作用。第1部分：不同多糖溶液的表面张力和流变行为
3. Rheological properties of printing pastes and their influence on quality-determining parameters in screen printing of cotton with reactive dyes using recycled polysaccharide thickeners [J] . Rebeka Fijan, Michele Basile, Romano Lapasin Carbohydrate Polymers: Scientific and Technological Aspects of Industrially Important Polysaccharides . 2009,第1期

机译：使用再生多糖增稠剂的活性染料对棉进行丝网印刷时，印刷浆料的流变性质及其对质量测定参数的影响
4. Interactions between non-ionic surfactant vesicles and peyer's patches - a clsm study [C] . C.-O. Rentel, P. V. garcia, A. Joob, International symposium on controlled release of bioactive materials;Consumer and diversified products conference . 1998

机译：非离子表面活性剂囊泡与淋巴集结之间的相互作用-CLSM研究
5. STUDIES ON THE USE OF SURFACTANT SYSTEMS IN ANALYTICAL CHEMISTRY. PART I. THE DETERMINATION OF THE DISSOCIATION CONSTANTS OF OXINE AND 2-METHYLOXINE IN THE PRESENCE OF MICELLE-FORMING SURFACTANTS. PART II. THE DETERMINATION OF SOME OF METAL IONS WITH OXINE AND 2-METHYLOXINE IN ANIONIC, CATIONIC AND NON-IONIC SURFACTANTS. PART III. THE DETERMINATION OF NITRITE WITH 2-METHYLOXINE IN CATIONIC SURFACTANT. PART IV. THE DETERMINATION OF METAL IONS WITH. [D] . TSAO, FU-PAO. 1981

机译：表面活性剂系统在分析化学中的应用研究。第一部分。形成胶束的表面活性剂存在下氧和2-甲基氧肟的离解常数的测定。第二部分阴离子表面活性剂，阳离子表面活性剂和非离子表面活性剂中一些金属离子的含量测定，分别采用氧化和2-甲氧基。第三部分阳离子表面活性剂中2-甲基氧肟酸的亚硝酸根的测定第四部分金属离子的测定。
6. Rheological studies on the effect of different thickeners in texture-modified chicken rendang for individuals with dysphagia [O] . Nuraihan Abu Zarim, Syahariza Zainul Abidin, Fazilah Ariffin 2018

机译：流变学研究不同增稠剂在吞咽困难患者质地改良的鸡当当中的作用
7. Spectrophotometric and conductometric studies of molecular interaction of brilliant cresyl blue with cationic, anionic and non-ionic surfactant in aqueous medium for application in photogalvanic cells for solar energy conversion and storage [O] . Chandrakanta Mall, Prem Prakash Solanki 2018

机译：用阳离子，阴离子和非离子表面活性剂在水性介质中应用阳离子，阴离子和非离子表面活性剂的分光光度法和传导研究，在太阳能转换和储存中的光致vanic细胞中的应用
8. Effect of polymer-surfactant interaction on the rheological properties of surfactant enhanced alkaline flooding formulations [R] . French, T. R., Josephson, C. B. 1993

机译：聚合物 - 表面活性剂相互作用对表面活性剂增强碱性驱油配方流变性的影响

Rheological study of interactions between non-ionic surfactants and polysaccharide thickeners used in textile printing

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